Hierarchical engineering of Large-caliber carbon Nanotube/Mesoporous Carbon/Fe₃C nanoparticle hybrid nanocomposite towards Ultra-lightweight electromagnetic microwave absorber

The rational regulation of the magnetic-dielectric composition and microstructures of the absorber is considered an important approach to optimize both the impedance matching and the electromagnetic microwave attenuation ability. Along these lines, a novel architecture-controlled large-caliber carbon nanotube/mesoporous carbon/Fe₃C nanoparticle-based hybrid nanocomposites (CNT/C/Fe₃C), which were derived from the CNT/polyimide (PI) assemblies anchoring ferric oxide hydrate nanoprecipitates, are presented in this work. The proposed configurations were prepared by applying a cooperative co-assembly strategy and high-temperature pyrolysis procedure for the development of an ultra-lightweight electromagnetic microwave absorber. The employed hierarchically tubular heterogeneous architecture is composed of a highly graphited CNT supporting skeleton, polyimide assemblies-converted carbon interlayer with mesopores, and uniformly distributed magnetic Fe₃C nanoparticles. This unique hierarchical structure can not only induce multiple reflection and scattering effects of the incident electromagnetic microwave but also trigger dipole/interfacial polarization, ferromagnetic resonance and eddy current loss that are beneficial for the synergistic dielectric and magnetic loss. Moreover, the large-caliber CNT and mesoporous carbon interlayer can endow the as-prepared absorber with lightweight characteristics. Hence, the proposed CNT/C-EDA/Fe₃C-900 hybrid nanocomposite exhibits a minimum reflection loss (RL) of −48.4 dB at a matching thickness of 3.2 mm, and the effective absorption bandwidth (RL ≤ -10 dB) almost covers the whole X-band only with a 5 wt% filler loading. Undoubtedly, these encouraging outcomes will promote the development of hierarchical engineering techniques of novel magnetic-dielectric nanocomposite absorbers.