General pore features for one-step C2H4 production from a C2 hydrocarbon mixture

Tao Zhang; Jian Wei Cao; Shu Yi Zhang; He Feng; Ye Li; Yu Wang; Juan Chen; Teng Wang; Kai Jie Chen

doi:10.1039/d2cc00177b

General pore features for one-step C₂H₄ production from a C2 hydrocarbon mixture

Tao Zhang, Jian Wei Cao, Shu Yi Zhang, He Feng, Ye Li, Yu Wang, Juan Chen, Teng Wang, Kai Jie Chen

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Herein, we propose the required general pore features for one-step C₂H₄ production from a C2 hydrocarbon mixture, such as: (i) a non-metallic binding site; (ii) polar pore surface; and (iii) narrow pocket. Four representative MOFs (Ni-BDC-INA, CPM-173, UiO-66, and DMOF-1) and two counterexamples (MOF-74-Co and IISERP-MOF2) were selected to verify this concept, by conducting single-component gas adsorption measurements, multiple-component breakthrough experiments, and molecular simulations. The established pore features are a stepping-stone for the design and synthesis of new MOFs with improved performance for C₂H₄ separation.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d2cc00177b
State	Accepted/In press - 2022

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title = "General pore features for one-step C2H4 production from a C2 hydrocarbon mixture",

abstract = "Herein, we propose the required general pore features for one-step C2H4 production from a C2 hydrocarbon mixture, such as: (i) a non-metallic binding site; (ii) polar pore surface; and (iii) narrow pocket. Four representative MOFs (Ni-BDC-INA, CPM-173, UiO-66, and DMOF-1) and two counterexamples (MOF-74-Co and IISERP-MOF2) were selected to verify this concept, by conducting single-component gas adsorption measurements, multiple-component breakthrough experiments, and molecular simulations. The established pore features are a stepping-stone for the design and synthesis of new MOFs with improved performance for C2H4 separation.",

author = "Tao Zhang and Cao, {Jian Wei} and Zhang, {Shu Yi} and He Feng and Ye Li and Yu Wang and Juan Chen and Teng Wang and Chen, {Kai Jie}",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",

year = "2022",

doi = "10.1039/d2cc00177b",

language = "英语",

journal = "Chemical Communications",

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T1 - General pore features for one-step C2H4 production from a C2 hydrocarbon mixture

AU - Zhang, Tao

AU - Cao, Jian Wei

AU - Zhang, Shu Yi

AU - Feng, He

AU - Li, Ye

AU - Wang, Yu

AU - Chen, Juan

AU - Wang, Teng

AU - Chen, Kai Jie

PY - 2022

Y1 - 2022

N2 - Herein, we propose the required general pore features for one-step C2H4 production from a C2 hydrocarbon mixture, such as: (i) a non-metallic binding site; (ii) polar pore surface; and (iii) narrow pocket. Four representative MOFs (Ni-BDC-INA, CPM-173, UiO-66, and DMOF-1) and two counterexamples (MOF-74-Co and IISERP-MOF2) were selected to verify this concept, by conducting single-component gas adsorption measurements, multiple-component breakthrough experiments, and molecular simulations. The established pore features are a stepping-stone for the design and synthesis of new MOFs with improved performance for C2H4 separation.

AB - Herein, we propose the required general pore features for one-step C2H4 production from a C2 hydrocarbon mixture, such as: (i) a non-metallic binding site; (ii) polar pore surface; and (iii) narrow pocket. Four representative MOFs (Ni-BDC-INA, CPM-173, UiO-66, and DMOF-1) and two counterexamples (MOF-74-Co and IISERP-MOF2) were selected to verify this concept, by conducting single-component gas adsorption measurements, multiple-component breakthrough experiments, and molecular simulations. The established pore features are a stepping-stone for the design and synthesis of new MOFs with improved performance for C2H4 separation.

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U2 - 10.1039/d2cc00177b

DO - 10.1039/d2cc00177b

M3 - 文章

C2 - 35299235

AN - SCOPUS:85127610522

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

General pore features for one-step C₂H₄ production from a C2 hydrocarbon mixture

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