Facilitative preparation of graphene/cellulose aerogels with tunable microwave absorption properties for ultra-lightweight applications

Graphene aerogels, as a novel type of carbon-based composite material, have shown great potential in the field of wave absorption due to its characteristics of high conductivity, adjustable structure and good corrosion resistance. It is of great significance to precisely control the dielectric properties of graphene aerogel composites by effectively adjusting their microstructures through the preparing process design, ultimately leading to improve their wave-absorbing performances. In this study, two kinds of graphene/cellulose aerogel composites with three-dimensional porous structures, were successfully prepared using graphene and short staple cellulose as raw materials via the freeze-drying method based on the dissolution-regeneration strategy. A comparative analysis was conducted to examine the differences of microstructures, dielectric properties and corresponding electromagnetic wave absorption performances, which reveals that the graphene/cellulose aerogel composites with graphene nanosheets incorporated into the cellulose matrix realize superior absorbing performances. The graphene/cellulose aerogel composite with a 32 wt% graphene addition realizes effective electromagnetic wave absorbing (reflection loss less than −10 dB) in the whole X-band (8–12.4 GHz) in a relatively large thickness range (3.9–4.7 mm). The densities of the proposed aerogel are no more than 0.02 g/cm³, demonstrating great potential for excellent lightweight microwave absorbing materials. The multiscale electromagnetic wave absorption mechanism is summarized, which would provide an important reference for designing ultra-lightweight absorbing materials with perfect absorption in wideband.