Charge-State Control of a Host Metal-Organic Framework Enabled by Axially Coordinated Tripyridine Ligand Alternation

Tao Zhang; Jian Wei Cao; Yi Fei Dai; He Feng; Shu Yi Zhang; Juan Chen; Teng Wang; Yu Wang; Kai Jie Chen

doi:10.1021/acs.cgd.2c00403

Charge-State Control of a Host Metal-Organic Framework Enabled by Axially Coordinated Tripyridine Ligand Alternation

Tao Zhang, Jian Wei Cao, Yi Fei Dai, He Feng, Shu Yi Zhang, Juan Chen, Teng Wang, Yu Wang, Kai Jie Chen

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Herein we demonstrate the charge-state control of a host framework by alternating the coordinating ligands in two isostructural metal-organic frameworks based on [Mn₃(μ₃-O)] clusters. The different charge states of two host frameworks were verified by multiple characterization techniques, altered methylene blue adsorption behavior and density functional theory calculations. The contribution of this study will provide useful guidelines for the future design of ionic coordination frameworks.

Original language	English
Pages (from-to)	3594-3600
Number of pages	7
Journal	Crystal Growth and Design
Volume	22
Issue number	6
DOIs	https://doi.org/10.1021/acs.cgd.2c00403
State	Published - 1 Jun 2022

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10.1021/acs.cgd.2c00403

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abstract = "Herein we demonstrate the charge-state control of a host framework by alternating the coordinating ligands in two isostructural metal-organic frameworks based on [Mn3(μ3-O)] clusters. The different charge states of two host frameworks were verified by multiple characterization techniques, altered methylene blue adsorption behavior and density functional theory calculations. The contribution of this study will provide useful guidelines for the future design of ionic coordination frameworks.",

author = "Tao Zhang and Cao, {Jian Wei} and Dai, {Yi Fei} and He Feng and Zhang, {Shu Yi} and Juan Chen and Teng Wang and Yu Wang and Chen, {Kai Jie}",

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T1 - Charge-State Control of a Host Metal-Organic Framework Enabled by Axially Coordinated Tripyridine Ligand Alternation

AU - Zhang, Tao

AU - Cao, Jian Wei

AU - Dai, Yi Fei

AU - Feng, He

AU - Zhang, Shu Yi

AU - Chen, Juan

AU - Wang, Teng

AU - Wang, Yu

AU - Chen, Kai Jie

PY - 2022/6/1

Y1 - 2022/6/1

N2 - Herein we demonstrate the charge-state control of a host framework by alternating the coordinating ligands in two isostructural metal-organic frameworks based on [Mn3(μ3-O)] clusters. The different charge states of two host frameworks were verified by multiple characterization techniques, altered methylene blue adsorption behavior and density functional theory calculations. The contribution of this study will provide useful guidelines for the future design of ionic coordination frameworks.

AB - Herein we demonstrate the charge-state control of a host framework by alternating the coordinating ligands in two isostructural metal-organic frameworks based on [Mn3(μ3-O)] clusters. The different charge states of two host frameworks were verified by multiple characterization techniques, altered methylene blue adsorption behavior and density functional theory calculations. The contribution of this study will provide useful guidelines for the future design of ionic coordination frameworks.

UR - http://www.scopus.com/inward/record.url?scp=85131803974&partnerID=8YFLogxK

U2 - 10.1021/acs.cgd.2c00403

DO - 10.1021/acs.cgd.2c00403

M3 - 文章

AN - SCOPUS:85131803974

SN - 1528-7483

VL - 22

SP - 3594

EP - 3600

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 6

ER -

Charge-State Control of a Host Metal-Organic Framework Enabled by Axially Coordinated Tripyridine Ligand Alternation

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