BF3·Et2O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors

Zheng Dong Liu; Yong Zheng Chang; Chang Jin Ou; Jin Yi Lin; Ling Hai Xie; Cheng Rong Yin; Ming Deng Yi; Yan Qian; Nai En Shi; Wei Huang

doi:10.1039/c1py00203a

BF₃·Et₂O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors

Zheng Dong Liu, Yong Zheng Chang, Chang Jin Ou, Jin Yi Lin, Ling Hai Xie, Cheng Rong Yin, Ming Deng Yi, Yan Qian, Nai En Shi, Wei Huang

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF₃·Et₂O-mediated Friedel-Crafts polymerization of AB, AB₂ and AB₄-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.

Original language	English
Pages (from-to)	2179-2182
Number of pages	4
Journal	Polymer Chemistry
Volume	2
Issue number	10
DOIs	https://doi.org/10.1039/c1py00203a
State	Published - Oct 2011
Externally published	Yes

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title = "BF3·Et2O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors",

abstract = "C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF3·Et2O-mediated Friedel-Crafts polymerization of AB, AB2 and AB4-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.",

author = "Liu, {Zheng Dong} and Chang, {Yong Zheng} and Ou, {Chang Jin} and Lin, {Jin Yi} and Xie, {Ling Hai} and Yin, {Cheng Rong} and Yi, {Ming Deng} and Yan Qian and Shi, {Nai En} and Wei Huang",

year = "2011",

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doi = "10.1039/c1py00203a",

language = "英语",

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AU - Liu, Zheng Dong

AU - Chang, Yong Zheng

AU - Ou, Chang Jin

AU - Lin, Jin Yi

AU - Xie, Ling Hai

AU - Yin, Cheng Rong

AU - Yi, Ming Deng

AU - Qian, Yan

AU - Shi, Nai En

AU - Huang, Wei

PY - 2011/10

Y1 - 2011/10

N2 - C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF3·Et2O-mediated Friedel-Crafts polymerization of AB, AB2 and AB4-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.

AB - C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF3·Et2O-mediated Friedel-Crafts polymerization of AB, AB2 and AB4-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.

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JO - Polymer Chemistry

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BF₃·Et₂O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors

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