[AEPH2][GeSb2S6]·CH3OH: A thiogermanate-thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye

Mei Ling Feng; Chun Li Hu; Kai Yao Wang; Cheng Feng Du; Xiao Ying Huang

doi:10.1039/c3ce40143j

[AEPH₂][GeSb₂S₆]·CH₃OH: A thiogermanate-thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb₃S₁₁} unit and exhibiting the ability of photocatalytic degradation of organic dye

Mei Ling Feng, Chun Li Hu, Kai Yao Wang, Cheng Feng Du, Xiao Ying Huang

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A new thiogermanate-thioantimonate, namely, [AEPH₂][GeSb ₂S₆]·CH₃OH (1) (AEP = N-(2-aminoethyl)piperazine) has been solvothermally synthesized, whose structure features a one-dimensional anionic ribbon of [GeSb₂S ₆]_n^2n- built of the firstly observed tetranuclear {GeSb₃S₁₁} cluster as secondary building unit. The photocatalytic study indicated that 1 was able to degrade Rhodamine B under visible irradiation.

Original language	English
Pages (from-to)	5007-5011
Number of pages	5
Journal	CrystEngComm
Volume	15
Issue number	25
DOIs	https://doi.org/10.1039/c3ce40143j
State	Published - 7 Jul 2013
Externally published	Yes

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10.1039/c3ce40143j

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@article{47b6d6bb368347f9b7a2da1b7e22be1f,

title = "[AEPH2][GeSb2S6]·CH3OH: A thiogermanate-thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye",

abstract = "A new thiogermanate-thioantimonate, namely, [AEPH2][GeSb 2S6]·CH3OH (1) (AEP = N-(2-aminoethyl)piperazine) has been solvothermally synthesized, whose structure features a one-dimensional anionic ribbon of [GeSb2S 6]n2n- built of the firstly observed tetranuclear {GeSb3S11} cluster as secondary building unit. The photocatalytic study indicated that 1 was able to degrade Rhodamine B under visible irradiation.",

author = "Feng, {Mei Ling} and Hu, {Chun Li} and Wang, {Kai Yao} and Du, {Cheng Feng} and Huang, {Xiao Ying}",

year = "2013",

month = jul,

day = "7",

doi = "10.1039/c3ce40143j",

language = "英语",

volume = "15",

pages = "5007--5011",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "25",

}

[AEPH₂][GeSb₂S₆]·CH₃OH: A thiogermanate-thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb₃S₁₁} unit and exhibiting the ability of photocatalytic degradation of organic dye. / Feng, Mei Ling; Hu, Chun Li; Wang, Kai Yao et al.
In: CrystEngComm, Vol. 15, No. 25, 07.07.2013, p. 5007-5011.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - [AEPH2][GeSb2S6]·CH3OH

T2 - A thiogermanate-thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye

AU - Feng, Mei Ling

AU - Hu, Chun Li

AU - Wang, Kai Yao

AU - Du, Cheng Feng

AU - Huang, Xiao Ying

PY - 2013/7/7

Y1 - 2013/7/7

N2 - A new thiogermanate-thioantimonate, namely, [AEPH2][GeSb 2S6]·CH3OH (1) (AEP = N-(2-aminoethyl)piperazine) has been solvothermally synthesized, whose structure features a one-dimensional anionic ribbon of [GeSb2S 6]n2n- built of the firstly observed tetranuclear {GeSb3S11} cluster as secondary building unit. The photocatalytic study indicated that 1 was able to degrade Rhodamine B under visible irradiation.

AB - A new thiogermanate-thioantimonate, namely, [AEPH2][GeSb 2S6]·CH3OH (1) (AEP = N-(2-aminoethyl)piperazine) has been solvothermally synthesized, whose structure features a one-dimensional anionic ribbon of [GeSb2S 6]n2n- built of the firstly observed tetranuclear {GeSb3S11} cluster as secondary building unit. The photocatalytic study indicated that 1 was able to degrade Rhodamine B under visible irradiation.

UR - http://www.scopus.com/inward/record.url?scp=84882384945&partnerID=8YFLogxK

U2 - 10.1039/c3ce40143j

DO - 10.1039/c3ce40143j

M3 - 文章

AN - SCOPUS:84882384945

SN - 1466-8033

VL - 15

SP - 5007

EP - 5011

JO - CrystEngComm

JF - CrystEngComm

IS - 25

ER -

[AEPH₂][GeSb₂S₆]·CH₃OH: A thiogermanate-thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb₃S₁₁} unit and exhibiting the ability of photocatalytic degradation of organic dye

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