A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO2 under mild and co-catalyst free conditions

Yun Hu Han; Zhong Yuan Zhou; Chong Bin Tian; Shao Wu Du

doi:10.1039/c6gc00413j

A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO₂ under mild and co-catalyst free conditions

Yun Hu Han, Zhong Yuan Zhou, Chong Bin Tian, Shao Wu Du

Research output: Contribution to journal › Article › peer-review

121 Scopus citations

Abstract

A novel 3D → 3D interpenetrated Zn-polyhedral MOF [Zn₆(TATAB)₄(DABCO)₃(H₂O)₃]·12DMF·9H₂O (1) (H₃TATAB = 4,4′,4′′-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. Owing to the high density of Lewis acid active sites and affinity to CO₂ of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with CO₂ into propylene carbonate under mild conditions (100 °C and ambient CO₂ pressure) with a high yield of 99% over 16 h. Moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.

Original language	English
Pages (from-to)	4086-4091
Number of pages	6
Journal	Green Chemistry
Volume	18
Issue number	14
DOIs	https://doi.org/10.1039/c6gc00413j
State	Published - 2016
Externally published	Yes

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title = "A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO2 under mild and co-catalyst free conditions",

abstract = "A novel 3D → 3D interpenetrated Zn-polyhedral MOF [Zn6(TATAB)4(DABCO)3(H2O)3]·12DMF·9H2O (1) (H3TATAB = 4,4′,4′′-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. Owing to the high density of Lewis acid active sites and affinity to CO2 of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with CO2 into propylene carbonate under mild conditions (100 °C and ambient CO2 pressure) with a high yield of 99% over 16 h. Moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.",

author = "Han, {Yun Hu} and Zhou, {Zhong Yuan} and Tian, {Chong Bin} and Du, {Shao Wu}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6gc00413j",

language = "英语",

volume = "18",

pages = "4086--4091",

journal = "Green Chemistry",

issn = "1463-9262",

publisher = "Royal Society of Chemistry",

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T1 - A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO2 under mild and co-catalyst free conditions

AU - Han, Yun Hu

AU - Zhou, Zhong Yuan

AU - Tian, Chong Bin

AU - Du, Shao Wu

PY - 2016

Y1 - 2016

N2 - A novel 3D → 3D interpenetrated Zn-polyhedral MOF [Zn6(TATAB)4(DABCO)3(H2O)3]·12DMF·9H2O (1) (H3TATAB = 4,4′,4′′-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. Owing to the high density of Lewis acid active sites and affinity to CO2 of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with CO2 into propylene carbonate under mild conditions (100 °C and ambient CO2 pressure) with a high yield of 99% over 16 h. Moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.

AB - A novel 3D → 3D interpenetrated Zn-polyhedral MOF [Zn6(TATAB)4(DABCO)3(H2O)3]·12DMF·9H2O (1) (H3TATAB = 4,4′,4′′-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. Owing to the high density of Lewis acid active sites and affinity to CO2 of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with CO2 into propylene carbonate under mild conditions (100 °C and ambient CO2 pressure) with a high yield of 99% over 16 h. Moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.

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U2 - 10.1039/c6gc00413j

DO - 10.1039/c6gc00413j

M3 - 文章

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SN - 1463-9262

VL - 18

SP - 4086

EP - 4091

JO - Green Chemistry

JF - Green Chemistry

IS - 14

ER -

A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO₂ under mild and co-catalyst free conditions

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