完全非晶态Ni-B合金镀层的电沉积制备

In order to solve the problem that it is difficult to prepare highly amorphous Ni-B alloy coating, the control variable method was used to explore the influence law of bath composition on the amorphous process of Ni-B alloy coating, and the electrodeposition method was used to prepare high-B amorphous Ni-B composite coating. X-ray diffraction (XRD) was used to characterize the phase structure of the sedimentary layer, and field emission scanning electron microscopy (FESEM) and energy spectrum analysis (EDS) were used to investigate the microscopic morphology and element distribution composition of the sedimentary layer. The results show that the sedimentary layer can be changed from crystalline state to amorphous state by controlling the composition of solution. The resulting sediments are highly amorphous. This system can be electrodeposited to obtain amorphous Ni-B alloy sediments with a complete, close and meticulous surface, and almost no metal crystal diffraction peak. The content of B in the sediments can be increased to 10.21%(mass fraction).