TY - JOUR
T1 - Unique Seamlessly Bonded CNT@Graphene Hybrid Nanostructure Introduced in an Interlayer for Efficient and Stable Perovskite Solar Cells
AU - Li, Xuanhua
AU - Tong, Tengteng
AU - Wu, Qinjiang
AU - Guo, Shaohui
AU - Song, Qiang
AU - Han, Jian
AU - Huang, Zhixiang
N1 - Publisher Copyright:
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2018/8/8
Y1 - 2018/8/8
N2 - Carbon nanomaterials have been widely used as an interlayer for realizing efficient and stable perovskite solar cells (PSCs). Theoretically, the design of a carbon composite interlayer that combines excellent conductivity with a high specific surface area is a better strategy than the application of pure nanocarbons. Here, an unusual seamlessly bonded carbon nanotube@graphene (CNT@G) hybrid nanomaterial was strategically synthesized and demonstrated to behave as an efficient interlayer for realizing efficient and stable PSCs. Due to the advantage of the seamless bond, the as-proposed hybrid nanostructure showed an apparent improvement compared to the use of CNTs only, graphene only, or a simple mixture of CNTs and graphene. The power conversion efficiency improved from 15.67% to 19.56% after introduction of the hybrid nanomaterial due to efficient carrier extraction, faster charge transport, and restrained carrier recombination. More importantly, PSCs with a CNT@G hybrid-decorated hole transport layer (HTL) showed good thermal stability during a 50 h heat-aging test at 100 °C and water stability under ambient humidity (30–50% relative humidity) for 500 h because the hybrid nanostructure exhibited an increased capability to block ion/molecule diffusion. Our results provide an alternative approach for fully exploring the potential application of nanocarbons in the development of high-performance PSCs.
AB - Carbon nanomaterials have been widely used as an interlayer for realizing efficient and stable perovskite solar cells (PSCs). Theoretically, the design of a carbon composite interlayer that combines excellent conductivity with a high specific surface area is a better strategy than the application of pure nanocarbons. Here, an unusual seamlessly bonded carbon nanotube@graphene (CNT@G) hybrid nanomaterial was strategically synthesized and demonstrated to behave as an efficient interlayer for realizing efficient and stable PSCs. Due to the advantage of the seamless bond, the as-proposed hybrid nanostructure showed an apparent improvement compared to the use of CNTs only, graphene only, or a simple mixture of CNTs and graphene. The power conversion efficiency improved from 15.67% to 19.56% after introduction of the hybrid nanomaterial due to efficient carrier extraction, faster charge transport, and restrained carrier recombination. More importantly, PSCs with a CNT@G hybrid-decorated hole transport layer (HTL) showed good thermal stability during a 50 h heat-aging test at 100 °C and water stability under ambient humidity (30–50% relative humidity) for 500 h because the hybrid nanostructure exhibited an increased capability to block ion/molecule diffusion. Our results provide an alternative approach for fully exploring the potential application of nanocarbons in the development of high-performance PSCs.
KW - carbon nanomaterials
KW - efficiency
KW - hybrid nanostructures
KW - perovskite solar cells
KW - stability
UR - http://www.scopus.com/inward/record.url?scp=85051146864&partnerID=8YFLogxK
U2 - 10.1002/adfm.201800475
DO - 10.1002/adfm.201800475
M3 - 文章
AN - SCOPUS:85051146864
SN - 1616-301X
VL - 28
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 32
M1 - 1800475
ER -