Unique Seamlessly Bonded CNT@Graphene Hybrid Nanostructure Introduced in an Interlayer for Efficient and Stable Perovskite Solar Cells

Xuanhua Li, Tengteng Tong, Qinjiang Wu, Shaohui Guo, Qiang Song, Jian Han, Zhixiang Huang

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55 引用 (Scopus)

摘要

Carbon nanomaterials have been widely used as an interlayer for realizing efficient and stable perovskite solar cells (PSCs). Theoretically, the design of a carbon composite interlayer that combines excellent conductivity with a high specific surface area is a better strategy than the application of pure nanocarbons. Here, an unusual seamlessly bonded carbon nanotube@graphene (CNT@G) hybrid nanomaterial was strategically synthesized and demonstrated to behave as an efficient interlayer for realizing efficient and stable PSCs. Due to the advantage of the seamless bond, the as-proposed hybrid nanostructure showed an apparent improvement compared to the use of CNTs only, graphene only, or a simple mixture of CNTs and graphene. The power conversion efficiency improved from 15.67% to 19.56% after introduction of the hybrid nanomaterial due to efficient carrier extraction, faster charge transport, and restrained carrier recombination. More importantly, PSCs with a CNT@G hybrid-decorated hole transport layer (HTL) showed good thermal stability during a 50 h heat-aging test at 100 °C and water stability under ambient humidity (30–50% relative humidity) for 500 h because the hybrid nanostructure exhibited an increased capability to block ion/molecule diffusion. Our results provide an alternative approach for fully exploring the potential application of nanocarbons in the development of high-performance PSCs.

源语言英语
文章编号1800475
期刊Advanced Functional Materials
28
32
DOI
出版状态已出版 - 8 8月 2018

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