Thickness-Dependence of 2D g-C3N4 Artificial Interface Layers on Lithium Metal Deposition

Pengbo Zhai, Qianqian He, Huaning Jiang, Binyin Gao, Bo Zhang, Qian Chen, Zhilin Yang, Tianshuai Wang, Yongji Gong

科研成果: 期刊稿件文章同行评审

19 引用 (Scopus)

摘要

Constructing artificial interfacial layers using 2D materials with tunable physicochemical properties is a promising strategy to fabricate high-performance lithium (Li) metal anodes. However, their structural evolution during solid-electrolyte interphase (SEI) formation and the thickness effects on charge transport remain elusive. Herein, 2D g-C3N4 layers with varied thicknesses are developed on the surface of copper foil to evaluate the thickness effects of artificial SEI on Li metal deposition. It is demonstrated that a thin g-C3N4 layer (≈2 nm) is rapidly decomposed and fractured under the impact of Li-ion flux, while a thick g-C3N4 layer (≈50 nm) impedes the transport of lithium ions and electrons simultaneously, hindering the Li metal deposition underneath. Notably, a g-C3N4 layer with moderate thickness (≈10 nm) dominates in-situ generation of stable g-C3N4/Li3N hybrid artificial SEI and enables fast Li-ion transport, which induces uniform Li deposition. The lithium electrode protected by the moderate-thickness g-C3N4 layer exhibits outstanding cycling stability with a high average Coulombic efficiency of ≈98.92% for over 380 cycles and enables stable cycling of full cell with 50% Li excess and lean electrolyte. This proof-of-concept study provides essential guidance for the application of 2D materials in constructing artificial SEI for Li metal anodes.

源语言英语
文章编号2302730
期刊Advanced Energy Materials
14
5
DOI
出版状态已出版 - 2 2月 2024

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