Thermally populated "bright" states for wide-range and high temperature sensing in air

Qiyun Fang, Jiewei Li, Shayu Li, Ruihong Duan, Shuangqing Wang, Yuanping Yi, Xudong Guo, Yan Qian, Wei Huang, Guoqiang Yang

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55 引用 (Scopus)

摘要

A series of air-stable triarylphosphine oxide-based thermosensitive ratiometric sensors based on local excited (LE) and charge transfer (CT) emissions have been designed and synthesized. The fluorescence intensity of tri(pyren-1-yl)phosphine oxide exhibits a prominent temperature-dependent feature over a wide temperature range due to thermally populated emissive LE states. The wide ratiometric temperature sensing range and high stability/reversibility in an ambient atmosphere indicate their great potentials in facile and practical applications.

源语言英语
页(从-至)5702-5705
页数4
期刊Chemical Communications
53
42
DOI
出版状态已出版 - 2017
已对外发布

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