TY - JOUR
T1 - Synthesis, characterization and excellent electromagnetic wave absorption properties of graphene/poly (3,4-ethylenedioxythiophene) hybrid materials with Fe3O4 nanoparticles
AU - Liu, Panbo
AU - Huang, Ying
AU - Zhang, Xiang
PY - 2014/12/25
Y1 - 2014/12/25
N2 - The electromagnetic wave absorption properties of the ternary nanocomposites consisting of graphene, poly (3,4-ethylenedioxythiophene) and Fe3O4 nanoparticles had never been reported. Herein, in order to expand the scope of electromagnetic wave absorption materials, the nanostructured graphene/poly (3,4-ethylenedioxythiophene) hybrid materials with Fe3O4 nanoparticles had been synthesized by a controllable co-precipitation method. The nanocomposites were characterized by FTIR, XRD, TEM, Raman spectroscopy, XPS and TG analysis. The investigation of the electromagnetic parameters revealed that the excellent electromagnetic wave absorption properties of the nanocomposites may be attributed to the improved impedance matching, the enhanced interfacial effects and the geometric effect. The maximum reflection loss of the nanocomposites was up to -56.5 dB at 8.9 GHz and the absorption bandwidths exceeding -10 dB were 3 GHz with a thickness of 2.9 mm. Furthermore, our development strategies expanded the scope of the electromagnetic wave absorption materials and confirmed that the modification of graphene with poly (3,4-ethylenedioxythiophene) and Fe3O4 nanoparticles makes the nanocomposites have a promising future in electromagnetic wave absorption materials.
AB - The electromagnetic wave absorption properties of the ternary nanocomposites consisting of graphene, poly (3,4-ethylenedioxythiophene) and Fe3O4 nanoparticles had never been reported. Herein, in order to expand the scope of electromagnetic wave absorption materials, the nanostructured graphene/poly (3,4-ethylenedioxythiophene) hybrid materials with Fe3O4 nanoparticles had been synthesized by a controllable co-precipitation method. The nanocomposites were characterized by FTIR, XRD, TEM, Raman spectroscopy, XPS and TG analysis. The investigation of the electromagnetic parameters revealed that the excellent electromagnetic wave absorption properties of the nanocomposites may be attributed to the improved impedance matching, the enhanced interfacial effects and the geometric effect. The maximum reflection loss of the nanocomposites was up to -56.5 dB at 8.9 GHz and the absorption bandwidths exceeding -10 dB were 3 GHz with a thickness of 2.9 mm. Furthermore, our development strategies expanded the scope of the electromagnetic wave absorption materials and confirmed that the modification of graphene with poly (3,4-ethylenedioxythiophene) and Fe3O4 nanoparticles makes the nanocomposites have a promising future in electromagnetic wave absorption materials.
KW - Composite materials
KW - Electromagnetic wave absorption properties
KW - Graphene
KW - Nanoparticles
KW - Polymers
UR - http://www.scopus.com/inward/record.url?scp=84906831213&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2014.08.103
DO - 10.1016/j.jallcom.2014.08.103
M3 - 文章
AN - SCOPUS:84906831213
SN - 0925-8388
VL - 617
SP - 511
EP - 517
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
ER -