Synthesis and quenching behavior of a novel cationic poly(p-phenylenevinylene) related copolymer

Guang Wei Zhang; Qu Li Fan; Wei Huang

Synthesis and quenching behavior of a novel cationic poly(p-phenylenevinylene) related copolymer

Guang Wei Zhang, Qu Li Fan, Wei Huang

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

A novel poly(p-phenylenevinylene) related copolymer was synthesized by Wittig reaction. The corresponding cationic conjugated polymer was successfully obtained via a post-polymerization approach. On the basis of ¹H NMR spectra, it was found that this phenyl-substituted PPV related copolymer is of 30% cis-vinylic linkage. The quenching effect of Fe(CN)₆^4- on the cationic PPV derivative was studied, and a downward Stern-Volmer curve was found.

源语言	英语
页（从-至）	413-416
页数	4
期刊	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
卷	30
期	2
出版状态	已出版 - 2月 2009
已对外发布	是

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abstract = "A novel poly(p-phenylenevinylene) related copolymer was synthesized by Wittig reaction. The corresponding cationic conjugated polymer was successfully obtained via a post-polymerization approach. On the basis of 1H NMR spectra, it was found that this phenyl-substituted PPV related copolymer is of 30% cis-vinylic linkage. The quenching effect of Fe(CN)64- on the cationic PPV derivative was studied, and a downward Stern-Volmer curve was found.",

keywords = "Conjugated polyelectrolytes, Poly(p-phenylenevinylene), Quenching effect",

author = "Zhang, {Guang Wei} and Fan, {Qu Li} and Wei Huang",

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AU - Fan, Qu Li

AU - Huang, Wei

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N2 - A novel poly(p-phenylenevinylene) related copolymer was synthesized by Wittig reaction. The corresponding cationic conjugated polymer was successfully obtained via a post-polymerization approach. On the basis of 1H NMR spectra, it was found that this phenyl-substituted PPV related copolymer is of 30% cis-vinylic linkage. The quenching effect of Fe(CN)64- on the cationic PPV derivative was studied, and a downward Stern-Volmer curve was found.

AB - A novel poly(p-phenylenevinylene) related copolymer was synthesized by Wittig reaction. The corresponding cationic conjugated polymer was successfully obtained via a post-polymerization approach. On the basis of 1H NMR spectra, it was found that this phenyl-substituted PPV related copolymer is of 30% cis-vinylic linkage. The quenching effect of Fe(CN)64- on the cationic PPV derivative was studied, and a downward Stern-Volmer curve was found.

KW - Conjugated polyelectrolytes

KW - Poly(p-phenylenevinylene)

KW - Quenching effect

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JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

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ER -

Synthesis and quenching behavior of a novel cationic poly(p-phenylenevinylene) related copolymer

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