Synthesis and characterization of a novel light-emitting copolymer with improved charge-balancing property

Y. Xiao, W. L. Yu, Z. K. Chen, N. H.S. Lee, Y. H. Lai, W. Huang

科研成果: 期刊稿件会议文章同行评审

9 引用 (Scopus)

摘要

A novel copolymer, M-DCN-11, was synthesized via the Wittig reaction by incorporating a highly electronegative unit, 2,5-dicyano-1,4-phenylenevinylene (DCN-PV), alternately into the backbone of MEH-PPV. The copolymer was characterized by elemental analysis, cyclic voltammetry, UV, PL, FTIR, GPC, etc. The copolymer has good solubility in common organic solvents and can be cast as quality thin films. It shows a partially reversible oxidation process with the oxidation potential onset at 1.1 V (vs. SCE), which is 0.8 V higher than that of MEH-PPV (0.3 V vs. SCE). The reversible reduction process shows four peaks at -1.2, -1.5, -1.6, and -1.8 V (vs. SCE), respectively, starting from -0.9 V (vs. SCE). These data indicate that the polymer has been changed from a typical hole injection and transport material to a typical electron injection and transport material after incorporating the moiety bearing strong electron-withdrawing groups (DCN-PV) into the backbone.

源语言英语
页(从-至)102-105
页数4
期刊Thin Solid Films
363
1
DOI
出版状态已出版 - 1 3月 2000
已对外发布
活动The Asia-Pacific Symposium on Organic Electroluminescent Materials and Devices - Hong Kong, Hong Kong
期限: 8 6月 199911 6月 1999

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