摘要
The photoisomerization behavior of mesogenic azobenzene makes it possible to convert light energy into mechanical action. However, achieving durability, configurability, and flexibility of light-responsive actuators for artificial intelligence applications remains challenging. Here, a light responsive polyurethane (AzoPU-SS) with remarkable anti-fatigue and anti-stress properties has been synthesized through the combination of dynamic disulfide bonds and mesogenic azobenzene functional groups. The AzoPU-SS film demonstrated excellent photo-induced bending, under ultraviolet (UV) light exposure, indicating effective transfer of molecular deformation from the microscopic to the macroscopic level. Moreover, the AzoPU-SS material's elongation at break was greatly increased, due to the dynamic and reversible nature of the flexible S-S and H bonds, enabling the coordinated motion of azobenzene groups and producing significant deformation. Such a reinforced strategy could be used to design smart actuators with superior stretchability and toughness, helping to broaden the applications of light-responsive actuator materials.
源语言 | 英语 |
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文章编号 | e56629 |
期刊 | Journal of Applied Polymer Science |
卷 | 142 |
期 | 12 |
DOI | |
出版状态 | 已出版 - 20 3月 2025 |
已对外发布 | 是 |