Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n

Hayley S. Scott; Alankriti Bajpai; Kai Jie Chen; Tony Pham; Brian Space; John J. Perry; Michael J. Zaworotko

doi:10.1039/c5cc05866j

Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)₂(Cr₂O₇)]_n

Hayley S. Scott, Alankriti Bajpai, Kai Jie Chen, Tony Pham, Brian Space, John J. Perry, Michael J. Zaworotko

科研成果: 期刊稿件 › 文章 › 同行评审

43 引用（Scopus）

摘要

A primitive cubic (pcu) network of formula [Ni(1,2-bis(4-pyridyl)acetylene)₂(Cr₂O₇)]_n, DICRO-2-Ni-i, has been synthesised and found to exhibit a novel type of inclined 2-fold interpenetration and an isosteric heat of adsorption (Q_st) of 30.5 kJ mol^-1 towards CO₂ at zero loading. Q_st is relatively high in the broad context but less than that observed in related hybrid ultramicroporous materials, a feature that can be understood after studying pore structure and molecular simulations of CO₂ adsorption.

源语言	英语
页（从-至）	14832-14835
页数	4
期刊	Chemical Communications
卷	51
期	80
DOI	https://doi.org/10.1039/c5cc05866j
出版状态	已出版 - 19 8月 2015
已对外发布	是

访问文件

10.1039/c5cc05866j

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{7ed5007c0ce940cd956cee66454dd584,

title = "Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n",

abstract = "A primitive cubic (pcu) network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n, DICRO-2-Ni-i, has been synthesised and found to exhibit a novel type of inclined 2-fold interpenetration and an isosteric heat of adsorption (Qst) of 30.5 kJ mol-1 towards CO2 at zero loading. Qst is relatively high in the broad context but less than that observed in related hybrid ultramicroporous materials, a feature that can be understood after studying pore structure and molecular simulations of CO2 adsorption.",

author = "Scott, {Hayley S.} and Alankriti Bajpai and Chen, {Kai Jie} and Tony Pham and Brian Space and Perry, {John J.} and Zaworotko, {Michael J.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

month = aug,

day = "19",

doi = "10.1039/c5cc05866j",

language = "英语",

volume = "51",

pages = "14832--14835",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "80",

}

TY - JOUR

T1 - Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n

AU - Scott, Hayley S.

AU - Bajpai, Alankriti

AU - Chen, Kai Jie

AU - Pham, Tony

AU - Space, Brian

AU - Perry, John J.

AU - Zaworotko, Michael J.

PY - 2015/8/19

Y1 - 2015/8/19

N2 - A primitive cubic (pcu) network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n, DICRO-2-Ni-i, has been synthesised and found to exhibit a novel type of inclined 2-fold interpenetration and an isosteric heat of adsorption (Qst) of 30.5 kJ mol-1 towards CO2 at zero loading. Qst is relatively high in the broad context but less than that observed in related hybrid ultramicroporous materials, a feature that can be understood after studying pore structure and molecular simulations of CO2 adsorption.

AB - A primitive cubic (pcu) network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n, DICRO-2-Ni-i, has been synthesised and found to exhibit a novel type of inclined 2-fold interpenetration and an isosteric heat of adsorption (Qst) of 30.5 kJ mol-1 towards CO2 at zero loading. Qst is relatively high in the broad context but less than that observed in related hybrid ultramicroporous materials, a feature that can be understood after studying pore structure and molecular simulations of CO2 adsorption.

UR - http://www.scopus.com/inward/record.url?scp=84942437162&partnerID=8YFLogxK

U2 - 10.1039/c5cc05866j

DO - 10.1039/c5cc05866j

M3 - 文章

AN - SCOPUS:84942437162

SN - 1359-7345

VL - 51

SP - 14832

EP - 14835

JO - Chemical Communications

JF - Chemical Communications

IS - 80

ER -

Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n

摘要

访问文件

其它文件与链接

指纹

引用此

Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)₂(Cr₂O₇)]_n