Inverse CO2/C2H2 separation assisted by coordinated water in a dysprosium(iii) metal-organic framework

Bo Kai Ling, Min Zeng, Tao Zhang, Jian Wei Cao, Rong Yang, Lu Cheng, Chi Yu Zhang, Yu Wang, Kai Jie Chen

科研成果: 期刊稿件文章同行评审

7 引用 (Scopus)

摘要

An ultramicroporous metal-organic framework (MOF) constructed from dysprosium(iii) and oxalate, termed Dy-F-oxa, is carefully studied for inverse separation of CO2 from C2H2. Adsorption experiments and modeling studies reveal that the high CO2 adsorption is attributed to the preferential sites for CO2 by coordinated water. After the equimolar gas mixture breakthrough experiment, C2H2 can be directly produced as a pure effluent.

源语言英语
页(从-至)10952-10955
页数4
期刊Chemical Communications
59
73
DOI
出版状态已出版 - 15 8月 2023

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