TY - JOUR
T1 - In-situ pyrolysis synthesis of multi-element (F, N, S) co-doped porous carbon nanospheres as lubricating additives with improved tribological behaviors
AU - Wang, Yixin
AU - Liu, Sha
AU - Cui, Yuhong
AU - Bai, Wei
AU - Liu, Shujuan
AU - Ye, Qian
AU - Zhou, Feng
AU - Liu, Weimin
N1 - Publisher Copyright:
© 2023 Elsevier Ltd
PY - 2024/1/31
Y1 - 2024/1/31
N2 - Herein, hyper-crosslinked polystyrene nanospheres (HPSs) were synthesized via emulsion polymerization and Friedel-Crafts reaction utilizing styrene as the primary raw material. The multielement (F, N, S) co-doped carbon nanospheres with enriching microporous structures were synthesized using ionic liquid ([EMIM]NTf2) assisted carbonization of HPSs under 400 °C. The fabricated carbon nanospheres exhibit excellent dispersion stability as well as remarkable anti-friction and anti-wear properties. In comparison to pure 500SN, the friction coefficient of the multielement (F, N, S) co-doped carbon nanospheres is reduced to 0.108, resulting in 81.9 % reduction in wear volume. Furthermore, the friction coefficient shows minimal fluctuation under different frequency and temperature conditions, which is significantly lower by 21.4 % and 31.6 % respectively compared to 500SN, while exhibiting an improved carrying capacity of up to 550 N. Through Raman spectroscopy, XPS, as well as FIB-TEM analysis, the result revealed that tribochemical reactions occur between the active elements within the nanospheres and the friction pairs leading to the formation of the composite protective film (40–70 nm) composed mainly of the deposition film and the frictional chemical protective film, achieving superior frictional performance.
AB - Herein, hyper-crosslinked polystyrene nanospheres (HPSs) were synthesized via emulsion polymerization and Friedel-Crafts reaction utilizing styrene as the primary raw material. The multielement (F, N, S) co-doped carbon nanospheres with enriching microporous structures were synthesized using ionic liquid ([EMIM]NTf2) assisted carbonization of HPSs under 400 °C. The fabricated carbon nanospheres exhibit excellent dispersion stability as well as remarkable anti-friction and anti-wear properties. In comparison to pure 500SN, the friction coefficient of the multielement (F, N, S) co-doped carbon nanospheres is reduced to 0.108, resulting in 81.9 % reduction in wear volume. Furthermore, the friction coefficient shows minimal fluctuation under different frequency and temperature conditions, which is significantly lower by 21.4 % and 31.6 % respectively compared to 500SN, while exhibiting an improved carrying capacity of up to 550 N. Through Raman spectroscopy, XPS, as well as FIB-TEM analysis, the result revealed that tribochemical reactions occur between the active elements within the nanospheres and the friction pairs leading to the formation of the composite protective film (40–70 nm) composed mainly of the deposition film and the frictional chemical protective film, achieving superior frictional performance.
KW - Anti-friction
KW - Anti-wear
KW - Carbon nanospheres
KW - Lubricant additives
KW - Polystyrene
UR - http://www.scopus.com/inward/record.url?scp=85179885289&partnerID=8YFLogxK
U2 - 10.1016/j.carbon.2023.118724
DO - 10.1016/j.carbon.2023.118724
M3 - 文章
AN - SCOPUS:85179885289
SN - 0008-6223
VL - 218
JO - Carbon
JF - Carbon
M1 - 118724
ER -