TY - JOUR
T1 - Facile preparation, high microwave absorption and microwave absorbing mechanism of RGO-Fe3O4 composites
AU - Zong, Meng
AU - Huang, Ying
AU - Zhao, Yang
AU - Sun, Xu
AU - Qu, Chunhao
AU - Luo, Didi
AU - Zheng, Jiangbo
PY - 2013/12/7
Y1 - 2013/12/7
N2 - Reduced graphene oxide (RGO)-Fe3O4 composites with obviously enhanced microwave absorption properties were successfully fabricated by a rational one-pot simplified co-precipitation route, which avoided the usage of an inert gas and any additional chemical agents (such as surfactants and stabilizers). Given these advantages, the strategy described in this study can be developed as a simple and large-scale route to yield RGO-Fe3O 4 composites. The morphology, structure, thermal stability, magnetic and microwave electromagnetic properties of the as-prepared composites were characterized by XRD, XPS, TEM, FT-IR, Raman, TG and VSM. These composites exhibit excellent microwave absorption properties, which are attributed to effective complementarities between the dielectric loss and the magnetic loss. The microwave absorption mechanism of the RGO-Fe3O4 composites was studied in detail. For the RGO-Fe3O4-3 composite, the maximum RL reaches -44.6 dB at 6.6 GHz with a thickness of 3.9 mm, and the bandwidth of RL less than -10 dB can reach up to 4.3 GHz (from 12.2 to 16.5 GHz) with a thickness of 2.0 mm. Moreover, the microwave absorption properties can be tuned easily by varying the (RGO)/(Fe3O4) ratio and layer thickness of the samples. It is believed that such composites will find wide applications in the microwave absorbing area.
AB - Reduced graphene oxide (RGO)-Fe3O4 composites with obviously enhanced microwave absorption properties were successfully fabricated by a rational one-pot simplified co-precipitation route, which avoided the usage of an inert gas and any additional chemical agents (such as surfactants and stabilizers). Given these advantages, the strategy described in this study can be developed as a simple and large-scale route to yield RGO-Fe3O 4 composites. The morphology, structure, thermal stability, magnetic and microwave electromagnetic properties of the as-prepared composites were characterized by XRD, XPS, TEM, FT-IR, Raman, TG and VSM. These composites exhibit excellent microwave absorption properties, which are attributed to effective complementarities between the dielectric loss and the magnetic loss. The microwave absorption mechanism of the RGO-Fe3O4 composites was studied in detail. For the RGO-Fe3O4-3 composite, the maximum RL reaches -44.6 dB at 6.6 GHz with a thickness of 3.9 mm, and the bandwidth of RL less than -10 dB can reach up to 4.3 GHz (from 12.2 to 16.5 GHz) with a thickness of 2.0 mm. Moreover, the microwave absorption properties can be tuned easily by varying the (RGO)/(Fe3O4) ratio and layer thickness of the samples. It is believed that such composites will find wide applications in the microwave absorbing area.
UR - http://www.scopus.com/inward/record.url?scp=84886853166&partnerID=8YFLogxK
U2 - 10.1039/c3ra43359e
DO - 10.1039/c3ra43359e
M3 - 文章
AN - SCOPUS:84886853166
SN - 2046-2069
VL - 3
SP - 23638
EP - 23648
JO - RSC Advances
JF - RSC Advances
IS - 45
ER -