Fabrication and thermoelectric properties of Ca-Co-O ceramics with negative Seebeck coefficient

Chunlin Gong, Zongmo Shi, Yi Zhang, Yongsheng Chen, Jiaxin Hu, Jianjun Gou, Mengjie Qin, Feng Gao

科研成果: 期刊稿件文章同行评审

17 引用 (Scopus)

摘要

Ca-Co-O ceramics is typically p-type thermoelectric materials and possesses positive Seebeck coefficient. In this work, n-type Ca-Co-O ceramics with negative Seebeck coefficients were fabricated by sintering and annealing in a reducing atmosphere. The microstructures and thermoelectric properties of the ceramics were investigated. The results show that the carrier concentration and the carrier mobility dramatically increase after the samples were annealed in the reducing atmosphere. The electrical resistivity increases from 0.0663 mΩ·cm to 0.2974 mΩ·cm, while the negative Seebeck coefficients varies from −24.9 μV/K to −56.3 μV/K as the temperature increases from 323 K to 823 K, and the maximum power factor (PF, 1.536 mW/m·K2) is obtained at 623 K. The samples have n-type thermoelectric properties with large PF values and ZT value (ZT = 0.39, 823 K). The unusual results will pave a new way for studying Ca-Co-O thermoelectric ceramics.

源语言英语
页(从-至)1233-1238
页数6
期刊Results in Physics
9
DOI
出版状态已出版 - 6月 2018

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