Electrochemical performance of iron and cobalt tetrapyrazinoporphyrazines supported on multiwalled carbon nanotubes

Sen Liu, Jinhua Lu, Hejun Li, Yingbo Fei

科研成果: 书/报告/会议事项章节会议稿件同行评审

1 引用 (Scopus)

摘要

Iron tetrapyrazinoporphyrazine (FePTpz) and cobalt tetrapyrazinoporphyrazines (CoPTpz) supported on multiwalled carbon nanotubes (MWCNTs) are prepared by solid phase synthesis method. The products are characterized by scanning and transmission electron microscopy. The electrocatalytic activity of the obtained MWCNTs-supported FePTpz and CoPTpz assemblies (MPTpz/MWCNTs) is measured by cyclic voltammetry and rotating disk electrode techniques in an oxygen-saturated 0.1M KOH. The results show that MPTpz/MWCNTs are more efficient than reference MPTpz. FePTpz/MWCNTs are more efficient for O2 reduction than CoPTpz/MWCNTs, both of FePTpz/MWCNTs and CoPTpz/MWCNTs exhibit a one-step, four-electron pathway for ORR.

源语言英语
主期刊名Advances in Chemical, Material and Metallurgical Engineering
2155-2159
页数5
版本1
DOI
出版状态已出版 - 2013
活动2012 2nd International Conference on Chemical, Material and Metallurgical Engineering, ICCMME 2012 - Kunming, 中国
期限: 15 12月 201216 12月 2012

出版系列

姓名Advanced Materials Research
编号1
634-638
ISSN(印刷版)1022-6680

会议

会议2012 2nd International Conference on Chemical, Material and Metallurgical Engineering, ICCMME 2012
国家/地区中国
Kunming
时期15/12/1216/12/12

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