Electrochemical impedance spectroscopy of poly (1-ethyl 3-(2-methacryloyloxy ethyl) imidazolium chloride) brushes with locally generated Pd

Bo Yu, Feng Zhou, Yu Bo, Xianming Hou, Weimin Liu

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摘要

The electrochemical impedance spectroscopy of polyelectrolyte brushes (poly (1-ethyl 3-(2-methacryloyloxy ethyl) imidazolium chloride) (PEMEIm-Cl) incorporated with locally generated palladium nanoparticles was first studied, which exhibits evidently different electrochemical behavior with the PEMEIm-Cl brushes in electrolyte solution. The PEMEIm-Cl brush containing Pd nanoparticles exhibits high electrocatalytic activity for the reduction of oxygen. Furthermore, the electrocatalytic activity of PEMEIm-Cl/Pd brush for oxygen reduction was highly tunable by changing the thickness of the composite film.

源语言英语
页(从-至)1749-1754
页数6
期刊Electrochemistry Communications
9
7
DOI
出版状态已出版 - 7月 2007
已对外发布

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