Electrochemical impedance analysis of perovskite-electrolyte interfaces

Zhen Li; Candy C. Mercado; Mengjin Yang; Ethan Palay; Kai Zhu

doi:10.1039/c6cc10315d

Electrochemical impedance analysis of perovskite-electrolyte interfaces

Zhen Li, Candy C. Mercado, Mengjin Yang, Ethan Palay, Kai Zhu

科研成果: 期刊稿件 › 文章 › 同行评审

49 引用（Scopus）

摘要

The flat band potentials and carrier densities of spin coated and sprayed MAPbI₃, FA_0.85Cs_0.15PbI₃, and MAPbBr₃ perovskite films were determined using the Mott-Schottky relation. The films developed a space charge layer and exhibited p-type conduction with a carrier concentration of ∼10¹⁶ cm⁻³ for spin coated films. Electrochemical impedance spectra showed typical space charge impedance at frequencies >1 kHz, and an exceptional high capacitance at frequency <1 kHz owing to an ion diffusion component.

源语言	英语
页（从-至）	2467-2470
页数	4
期刊	Chemical Communications
卷	53
期	16
DOI	https://doi.org/10.1039/c6cc10315d
出版状态	已出版 - 2017
已对外发布	是

访问文件

10.1039/c6cc10315d

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{e5568ba4487c410b98f96a344309fe33,

title = "Electrochemical impedance analysis of perovskite-electrolyte interfaces",

abstract = "The flat band potentials and carrier densities of spin coated and sprayed MAPbI3, FA0.85Cs0.15PbI3, and MAPbBr3 perovskite films were determined using the Mott-Schottky relation. The films developed a space charge layer and exhibited p-type conduction with a carrier concentration of ∼1016 cm−3 for spin coated films. Electrochemical impedance spectra showed typical space charge impedance at frequencies >1 kHz, and an exceptional high capacitance at frequency <1 kHz owing to an ion diffusion component.",

author = "Zhen Li and Mercado, {Candy C.} and Mengjin Yang and Ethan Palay and Kai Zhu",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6cc10315d",

language = "英语",

volume = "53",

pages = "2467--2470",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Electrochemical impedance analysis of perovskite-electrolyte interfaces

AU - Li, Zhen

AU - Mercado, Candy C.

AU - Yang, Mengjin

AU - Palay, Ethan

AU - Zhu, Kai

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - The flat band potentials and carrier densities of spin coated and sprayed MAPbI3, FA0.85Cs0.15PbI3, and MAPbBr3 perovskite films were determined using the Mott-Schottky relation. The films developed a space charge layer and exhibited p-type conduction with a carrier concentration of ∼1016 cm−3 for spin coated films. Electrochemical impedance spectra showed typical space charge impedance at frequencies >1 kHz, and an exceptional high capacitance at frequency <1 kHz owing to an ion diffusion component.

AB - The flat band potentials and carrier densities of spin coated and sprayed MAPbI3, FA0.85Cs0.15PbI3, and MAPbBr3 perovskite films were determined using the Mott-Schottky relation. The films developed a space charge layer and exhibited p-type conduction with a carrier concentration of ∼1016 cm−3 for spin coated films. Electrochemical impedance spectra showed typical space charge impedance at frequencies >1 kHz, and an exceptional high capacitance at frequency <1 kHz owing to an ion diffusion component.

UR - http://www.scopus.com/inward/record.url?scp=85013422753&partnerID=8YFLogxK

U2 - 10.1039/c6cc10315d

DO - 10.1039/c6cc10315d

M3 - 文章

C2 - 28180211

AN - SCOPUS:85013422753

SN - 1359-7345

VL - 53

SP - 2467

EP - 2470

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Electrochemical impedance analysis of perovskite-electrolyte interfaces

摘要

访问文件

其它文件与链接

指纹

引用此