摘要
A new strategy has been developed to directly synthesize two-dimensional metal-organic framework nanoplates in an aqueous system without any additives. Time-dependent experiments demonstrate that formation mechanisms mainly include limited diffusion of reactants in transient phase and capping-agent-like effect of HOOC-CH=CH-COO-. The obtained 2D MIL-53(Al)-FA exhibited intrinsic surface functional groups (-COOH) and accessible pores. Ag nanoparticles loaded on 2D product via electrostatic interactions between -COOH and positive Ag+ could accelerate catalytic decolorization of methyl orange in the presence of NaBH4. Furthermore, the product could be a good candidate for adsorption of gaseous iodine due to accessibility of the pores.
源语言 | 英语 |
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页(从-至) | 1378-1382 |
页数 | 5 |
期刊 | Crystal Growth and Design |
卷 | 20 |
期 | 3 |
DOI | |
出版状态 | 已出版 - 4 3月 2020 |