TY - JOUR
T1 - Crown Ether-Based Supramolecular Polymers
T2 - From Synthesis to Self-Assembly
AU - Duan, Zhaozhao
AU - Xu, Fenfen
AU - Huang, Xiaohui
AU - Qian, Yongchao
AU - Li, Hui
AU - Tian, Wei
N1 - Publisher Copyright:
© 2021 Wiley-VCH GmbH.
PY - 2022/7
Y1 - 2022/7
N2 - Supramolecular polymers not only possess many advantages of traditional polymers, but also have many unique characteristics. Supramolecular polymers can be constructed by self-assembly of various noncovalent interactions. Host–guest interaction, as one important type of noncovalent interactions, has been widely applied to construct supramolecular polymers. From the perspective of classification of the recognition system motifs, host–guest recognition motifs mainly include crown ether, cyclodextrin, calixarene, cucurbituril, and pillararene-based host–guest recognition pairs. Crown ethers, as the first-generation macrocyclic hosts, have played a very important part in the development of supramolecular chemistry. Due to the easy modification of crown ethers, various crown ether derivatives have been prepared by attaching some functional groups to the edges of crown ethers, which endowed them with some interesting properties and made them ideal candidates for the fabrication of supramolecular polymers. This review gives a review of the preparation of crown ether-based supramolecular polymers (CSPs) and summarizes crown ether-based recognition pairs, organization methods, topological structures, stimuli-responsiveness, and functional characteristics.
AB - Supramolecular polymers not only possess many advantages of traditional polymers, but also have many unique characteristics. Supramolecular polymers can be constructed by self-assembly of various noncovalent interactions. Host–guest interaction, as one important type of noncovalent interactions, has been widely applied to construct supramolecular polymers. From the perspective of classification of the recognition system motifs, host–guest recognition motifs mainly include crown ether, cyclodextrin, calixarene, cucurbituril, and pillararene-based host–guest recognition pairs. Crown ethers, as the first-generation macrocyclic hosts, have played a very important part in the development of supramolecular chemistry. Due to the easy modification of crown ethers, various crown ether derivatives have been prepared by attaching some functional groups to the edges of crown ethers, which endowed them with some interesting properties and made them ideal candidates for the fabrication of supramolecular polymers. This review gives a review of the preparation of crown ether-based supramolecular polymers (CSPs) and summarizes crown ether-based recognition pairs, organization methods, topological structures, stimuli-responsiveness, and functional characteristics.
KW - crown ethers
KW - host–guest recognitions
KW - self-assembly
KW - supramolecular polymers
UR - http://www.scopus.com/inward/record.url?scp=85121591685&partnerID=8YFLogxK
U2 - 10.1002/marc.202100775
DO - 10.1002/marc.202100775
M3 - 文献综述
C2 - 34882882
AN - SCOPUS:85121591685
SN - 1022-1336
VL - 43
JO - Macromolecular Rapid Communications
JF - Macromolecular Rapid Communications
IS - 14
M1 - 2100775
ER -