TY - JOUR
T1 - Compartmentalization within Self-Assembled Metal–Organic Framework Nanoparticles for Tandem Reactions
AU - Xu, Zhiling
AU - Xiao, Gengwu
AU - Li, Hongfeng
AU - Shen, Yu
AU - Zhang, Jing
AU - Pan, Ting
AU - Chen, Xinyi
AU - Zheng, Bing
AU - Wu, Jiansheng
AU - Li, Sheng
AU - Zhang, Weina
AU - Huang, Wei
AU - Huo, Fengwei
N1 - Publisher Copyright:
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2018/8/22
Y1 - 2018/8/22
N2 - Compartmentalization is an essential feature found in living cells to ensure multiple biological processes occur without being affected by undesired external influences. Here, compartmentalized systems are developed based on the self-assembly of metal–organic framework (MOF) nanoparticles into multifunctional MOF capsules (MOF-Cs). Such MOF-Cs have the capability of controlling molecular transportation and protecting interior microenvironment, thus making tandem reaction along trajectories to desired products. First of all, MOF-Cs present controlled molecular transportation derived from molecular sieving property of MOFs. Second, MOF-Cs can protect the encapsulated cargoes from denaturation and maintain their catalytic activity. Third, MOF-Cs can provide spatial segregation for incompatible species and facilitate communication between these compartments to perform tandem reactions. These compartmentalized structures offer new views in the transportation, microreactor, and biotechnology.
AB - Compartmentalization is an essential feature found in living cells to ensure multiple biological processes occur without being affected by undesired external influences. Here, compartmentalized systems are developed based on the self-assembly of metal–organic framework (MOF) nanoparticles into multifunctional MOF capsules (MOF-Cs). Such MOF-Cs have the capability of controlling molecular transportation and protecting interior microenvironment, thus making tandem reaction along trajectories to desired products. First of all, MOF-Cs present controlled molecular transportation derived from molecular sieving property of MOFs. Second, MOF-Cs can protect the encapsulated cargoes from denaturation and maintain their catalytic activity. Third, MOF-Cs can provide spatial segregation for incompatible species and facilitate communication between these compartments to perform tandem reactions. These compartmentalized structures offer new views in the transportation, microreactor, and biotechnology.
KW - compartmentalization
KW - controlled molecular transport
KW - metal–organic frameworks
KW - self-assembly
KW - tandem reactions
UR - http://www.scopus.com/inward/record.url?scp=85051801820&partnerID=8YFLogxK
U2 - 10.1002/adfm.201802479
DO - 10.1002/adfm.201802479
M3 - 文章
AN - SCOPUS:85051801820
SN - 1616-301X
VL - 28
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 34
M1 - 1802479
ER -