Balanced Mechanical and Biotribological Properties of Polymer Composites Reinforced by a 3D Interlocked Si₃N₄Nanowire Membrane

Polymer composites have great potential applications in the hip joint replacement, where the combinations of high mechanical strength and excellent biotribological properties are required. In this work, a well-dispersed three-dimensional (3D) silicon nitride nanowire membrane (SNm) designed as a reinforcement and brushite (Bs) served as bioactive filler are constructed into the polymer matrix, forming SNm-reinforced Bs/polymer composites (SNm-Bs/Pm). Especially, SNm could form a 3D interlocked structure, where the ultralong silicon nitride nanowires are entangled with each other. SNm could effectively facilitate the penetration of the polymer matrix and improve the cohesion strength of the polymer, thereby promoting mechanical and biotribological properties for SNm-Bs/Pm. The performances for polymer composites are optimized by increasing the layer number of preform. By comparing SNm-Bs/Pm with one-layer preform, the tensile strength of SNm-Bs/Pm with six-layer preforms reaches 83.3 MPa with an increase of 767.7%. In addition, the friction coefficient and wear rate of SNm-Bs/Pm with six-layer preforms in fetal bovine serum medium achieve 0.06 and 0.21 × 10^-14m³(N·m)^-1and decrease by 82.4 and 72.4%, respectively. The present work provides a promising methodology of preparing interlocked SNm-reinforced polymer composites with enhanced mechanical and biotribological properties that are potential for hip joint replacement applications.