A novel polyamide-type cyclophosphazene functionalized rGO/WS                         2                          nanosheets for bismaleimide resin with enhanced mechanical and tribological properties

Zhengyan Chen; Hongxia Yan; Liulong Guo; Lin Li; Pengfei Yang; Biao Liu

doi:10.1016/j.compositesa.2019.03.003

A novel polyamide-type cyclophosphazene functionalized rGO/WS ₂ nanosheets for bismaleimide resin with enhanced mechanical and tribological properties

Zhengyan Chen, Hongxia Yan, Liulong Guo, Lin Li, Pengfei Yang, Biao Liu

化学与化工学院

Northwestern Polytechnical University Xian

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41 引用（Scopus）

摘要

Bismaleimide (BMI) composites reinforced with novel polyamide-type cyclophosphazene functionalized rGO/WS ₂ were successfully fabricated in this paper. RGO/WS ₂ was firstly functionalized with polyphosphazene (poly (cyclophosphazene-co-branched polyethylenimine)) (PHbP) by a simple precipitation polymerization approach. The microstructure and morphology of as-prepared PHbP@rGO/WS ₂ were characterized detailedly. The mechanical and tribological properties of virgin BMI and its composites with various amounts of nano-filler (0.2–1.0 wt%) were comparatively investigated. The largest improvements in impact and flexural strengths of BMI composite (21.2 kJ/m ² and 185.7 MPa, respectively) were observed when the content of PHbP@rGO/WS ₂ was only 0.8 wt% and 0.6 wt%, increased by 82.8% and 52.0% than those of pure BMI. Furthermore, 0.6 wt% BMI system exhibited the lowest friction coefficient (0.13) and volume wear rate (1.22 × 10 ⁻⁶ mm ³ /(N·m)), decreased by 69.0% and 92.6% than neat BMI. This is owing to the good dispersibility and self-lubricity of PHbP@rGO/WS ₂ , strong interfacial strength between filler and BMI matrix.

源语言	英语
页（从-至）	18-27
页数	10
期刊	Composites Part A: Applied Science and Manufacturing
卷	121
DOI	https://doi.org/10.1016/j.compositesa.2019.03.003
出版状态	已出版 - 6月 2019

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10.1016/j.compositesa.2019.03.003

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Chen, Z., Yan, H., Guo, L., Li, L., Yang, P., & Liu, B. (2019). A novel polyamide-type cyclophosphazene functionalized rGO/WS ₂ nanosheets for bismaleimide resin with enhanced mechanical and tribological properties Composites Part A: Applied Science and Manufacturing, 121, 18-27. https://doi.org/10.1016/j.compositesa.2019.03.003

Chen, Zhengyan ; Yan, Hongxia ; Guo, Liulong 等. / A novel polyamide-type cyclophosphazene functionalized rGO/WS ₂ nanosheets for bismaleimide resin with enhanced mechanical and tribological properties 在: Composites Part A: Applied Science and Manufacturing. 2019 ; 卷 121. 页码 18-27.

@article{aae28133156f4eb5a3d51bf68b0bacf3,

title = " A novel polyamide-type cyclophosphazene functionalized rGO/WS 2 nanosheets for bismaleimide resin with enhanced mechanical and tribological properties ",

abstract = " Bismaleimide (BMI) composites reinforced with novel polyamide-type cyclophosphazene functionalized rGO/WS 2 were successfully fabricated in this paper. RGO/WS 2 was firstly functionalized with polyphosphazene (poly (cyclophosphazene-co-branched polyethylenimine)) (PHbP) by a simple precipitation polymerization approach. The microstructure and morphology of as-prepared PHbP@rGO/WS 2 were characterized detailedly. The mechanical and tribological properties of virgin BMI and its composites with various amounts of nano-filler (0.2–1.0 wt%) were comparatively investigated. The largest improvements in impact and flexural strengths of BMI composite (21.2 kJ/m 2 and 185.7 MPa, respectively) were observed when the content of PHbP@rGO/WS 2 was only 0.8 wt% and 0.6 wt%, increased by 82.8% and 52.0% than those of pure BMI. Furthermore, 0.6 wt% BMI system exhibited the lowest friction coefficient (0.13) and volume wear rate (1.22 × 10 −6 mm 3 /(N·m)), decreased by 69.0% and 92.6% than neat BMI. This is owing to the good dispersibility and self-lubricity of PHbP@rGO/WS 2 , strong interfacial strength between filler and BMI matrix.",

keywords = "Cyclophosphazene, Graphene/WS, Mechanical and tribological properties, Nanocomposites",

author = "Zhengyan Chen and Hongxia Yan and Liulong Guo and Lin Li and Pengfei Yang and Biao Liu",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2019",

month = jun,

doi = "10.1016/j.compositesa.2019.03.003",

language = "英语",

volume = "121",

pages = "18--27",

journal = "Composites Part A: Applied Science and Manufacturing",

issn = "1359-835X",

publisher = "Elsevier Ltd",

}

Chen, Z, Yan, H, Guo, L, Li, L, Yang, P & Liu, B 2019, ' A novel polyamide-type cyclophosphazene functionalized rGO/WS ₂ nanosheets for bismaleimide resin with enhanced mechanical and tribological properties ', Composites Part A: Applied Science and Manufacturing, 卷 121, 页码 18-27. https://doi.org/10.1016/j.compositesa.2019.03.003

A novel polyamide-type cyclophosphazene functionalized rGO/WS ₂ nanosheets for bismaleimide resin with enhanced mechanical and tribological properties . / Chen, Zhengyan; Yan, Hongxia; Guo, Liulong 等.
在: Composites Part A: Applied Science and Manufacturing, 卷 121, 06.2019, 页码 18-27.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - A novel polyamide-type cyclophosphazene functionalized rGO/WS 2 nanosheets for bismaleimide resin with enhanced mechanical and tribological properties

AU - Chen, Zhengyan

AU - Yan, Hongxia

AU - Guo, Liulong

AU - Li, Lin

AU - Yang, Pengfei

AU - Liu, Biao

PY - 2019/6

Y1 - 2019/6

N2 - Bismaleimide (BMI) composites reinforced with novel polyamide-type cyclophosphazene functionalized rGO/WS 2 were successfully fabricated in this paper. RGO/WS 2 was firstly functionalized with polyphosphazene (poly (cyclophosphazene-co-branched polyethylenimine)) (PHbP) by a simple precipitation polymerization approach. The microstructure and morphology of as-prepared PHbP@rGO/WS 2 were characterized detailedly. The mechanical and tribological properties of virgin BMI and its composites with various amounts of nano-filler (0.2–1.0 wt%) were comparatively investigated. The largest improvements in impact and flexural strengths of BMI composite (21.2 kJ/m 2 and 185.7 MPa, respectively) were observed when the content of PHbP@rGO/WS 2 was only 0.8 wt% and 0.6 wt%, increased by 82.8% and 52.0% than those of pure BMI. Furthermore, 0.6 wt% BMI system exhibited the lowest friction coefficient (0.13) and volume wear rate (1.22 × 10 −6 mm 3 /(N·m)), decreased by 69.0% and 92.6% than neat BMI. This is owing to the good dispersibility and self-lubricity of PHbP@rGO/WS 2 , strong interfacial strength between filler and BMI matrix.

AB - Bismaleimide (BMI) composites reinforced with novel polyamide-type cyclophosphazene functionalized rGO/WS 2 were successfully fabricated in this paper. RGO/WS 2 was firstly functionalized with polyphosphazene (poly (cyclophosphazene-co-branched polyethylenimine)) (PHbP) by a simple precipitation polymerization approach. The microstructure and morphology of as-prepared PHbP@rGO/WS 2 were characterized detailedly. The mechanical and tribological properties of virgin BMI and its composites with various amounts of nano-filler (0.2–1.0 wt%) were comparatively investigated. The largest improvements in impact and flexural strengths of BMI composite (21.2 kJ/m 2 and 185.7 MPa, respectively) were observed when the content of PHbP@rGO/WS 2 was only 0.8 wt% and 0.6 wt%, increased by 82.8% and 52.0% than those of pure BMI. Furthermore, 0.6 wt% BMI system exhibited the lowest friction coefficient (0.13) and volume wear rate (1.22 × 10 −6 mm 3 /(N·m)), decreased by 69.0% and 92.6% than neat BMI. This is owing to the good dispersibility and self-lubricity of PHbP@rGO/WS 2 , strong interfacial strength between filler and BMI matrix.

KW - Cyclophosphazene

KW - Graphene/WS

KW - Mechanical and tribological properties

KW - Nanocomposites

UR - http://www.scopus.com/inward/record.url?scp=85062712566&partnerID=8YFLogxK

U2 - 10.1016/j.compositesa.2019.03.003

DO - 10.1016/j.compositesa.2019.03.003

M3 - 文章

AN - SCOPUS:85062712566

SN - 1359-835X

VL - 121

SP - 18

EP - 27

JO - Composites Part A: Applied Science and Manufacturing

JF - Composites Part A: Applied Science and Manufacturing

ER -

Chen Z, Yan H, Guo L, Li L, Yang P, Liu B. A novel polyamide-type cyclophosphazene functionalized rGO/WS ₂ nanosheets for bismaleimide resin with enhanced mechanical and tribological properties Composites Part A: Applied Science and Manufacturing. 2019 6月;121:18-27. doi: 10.1016/j.compositesa.2019.03.003

A novel polyamide-type cyclophosphazene functionalized rGO/WS 2 nanosheets for bismaleimide resin with enhanced mechanical and tribological properties

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A novel polyamide-type cyclophosphazene functionalized rGO/WS ₂ nanosheets for bismaleimide resin with enhanced mechanical and tribological properties