A facile synthesis and the asymmetric catalytic activity of BINOL-based thiazole (thiadiazole) thioether ligands

Zhi Bing Dong, Bing Liu, Cao Fang, Jin Shan Li

科研成果: 期刊稿件文章同行评审

10 引用 (Scopus)

摘要

Four new BINOL-based thiazole (thiadiazole) thioether ligands (S)-1, (S)-2, (S,S)-3 and (S)-4 were prepared. When their catalytic effectiveness was tested, good results (up to 93% ee and 97% yield) were obtained in the asymmetric addition of diethylzinc to aldehydes while poor results were obtained in the asymmetric conjugate addition of diethylzinc to enones.

源语言英语
页(从-至)17-22
页数6
期刊Journal of Organometallic Chemistry
693
1
DOI
出版状态已出版 - 1 1月 2008
已对外发布

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