TY - JOUR
T1 - 1,9-Dicarbonyl-2,8-dioxo-butyne-ester Ferrocenophane
T2 - Synthesis, Structure and Recognition Properties for Co2+ and Cu2+ Ions
AU - Liu, Xiaoju
AU - Ren, Guoyu
AU - Ma, Xiangrong
AU - Xiang, Yulin
AU - Gao, Liguo
AU - Ma, Xiaoyan
N1 - Publisher Copyright:
© 2017, Pleiades Publishing, Ltd.
PY - 2017/12/1
Y1 - 2017/12/1
N2 - An efficient highly diluted synthetic approach to the synthesis of 1,9-dicarbonyl-2,8-dioxo-butyne ester ferrocenophane (L) has been developed. The title compound was characterized by IR, UV, FL, 1H NMR, spectroscopies, elemental analysis and so on. Further complex L shows fluorescence responses to Co2+ and Cu2+ in CH3OH, The results indicate that the complex could be applied in multianayte detection. The binding ability of receptor L CH3OH was tested for various cations (Co2+, Cu2+, Zn2+, and Ni2+ in water) and the binding constants for Co2+ and Cu2+ were the computed, having a distinct absorbance shift. The receptor is a very attractive array because its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in the area of biology, environmental sciences and material chemistry.
AB - An efficient highly diluted synthetic approach to the synthesis of 1,9-dicarbonyl-2,8-dioxo-butyne ester ferrocenophane (L) has been developed. The title compound was characterized by IR, UV, FL, 1H NMR, spectroscopies, elemental analysis and so on. Further complex L shows fluorescence responses to Co2+ and Cu2+ in CH3OH, The results indicate that the complex could be applied in multianayte detection. The binding ability of receptor L CH3OH was tested for various cations (Co2+, Cu2+, Zn2+, and Ni2+ in water) and the binding constants for Co2+ and Cu2+ were the computed, having a distinct absorbance shift. The receptor is a very attractive array because its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in the area of biology, environmental sciences and material chemistry.
UR - http://www.scopus.com/inward/record.url?scp=85045279448&partnerID=8YFLogxK
U2 - 10.1134/S1070427217120187
DO - 10.1134/S1070427217120187
M3 - 文章
AN - SCOPUS:85045279448
SN - 1070-4272
VL - 90
SP - 2016
EP - 2018
JO - Russian Journal of Applied Chemistry
JF - Russian Journal of Applied Chemistry
IS - 12
ER -