Unusual heterometallic ZnMg(COO) 3 building blocks for the construction of a homochiral srs-type metal-organic framework

Hui Yang; Tie Hu Li; Fei Wang; Jian Zhang

doi:10.1016/j.inoche.2011.11.039

Unusual heterometallic ZnMg(COO) ₃ building blocks for the construction of a homochiral srs-type metal-organic framework

Hui Yang, Tie Hu Li, Fei Wang, Jian Zhang

School of Materials Sience and Engineering

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A new homochiral metal-organic framework [ZnMg(btc)(H ₂O) ₄](NO ₃) (1, btc = 1,3,5-benzenetricarboxylate) with unusual 3-connected heterometallic ZnMg(COO) ₃ building blocks has been solvothermally synthesized and structurally characterized with the aid of single crystal X-ray diffraction. Compound 1 crystallizes in a chiral space group and exhibits 3-connected srs structural topology. The results reveal the first srs-type metal-organic framework constructed from heterometallic building blocks.

Original language	English
Pages (from-to)	86-88
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	16
DOIs	https://doi.org/10.1016/j.inoche.2011.11.039
State	Published - Feb 2012

Keywords

Chiral
Crystal structure
Metal-organic framework
Topology
Zinc

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10.1016/j.inoche.2011.11.039

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title = "Unusual heterometallic ZnMg(COO) 3 building blocks for the construction of a homochiral srs-type metal-organic framework",

abstract = "A new homochiral metal-organic framework [ZnMg(btc)(H 2O) 4](NO 3) (1, btc = 1,3,5-benzenetricarboxylate) with unusual 3-connected heterometallic ZnMg(COO) 3 building blocks has been solvothermally synthesized and structurally characterized with the aid of single crystal X-ray diffraction. Compound 1 crystallizes in a chiral space group and exhibits 3-connected srs structural topology. The results reveal the first srs-type metal-organic framework constructed from heterometallic building blocks.",

keywords = "Chiral, Crystal structure, Metal-organic framework, Topology, Zinc",

author = "Hui Yang and Li, {Tie Hu} and Fei Wang and Jian Zhang",

year = "2012",

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doi = "10.1016/j.inoche.2011.11.039",

language = "英语",

volume = "16",

pages = "86--88",

journal = "Inorganic Chemistry Communications",

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T1 - Unusual heterometallic ZnMg(COO) 3 building blocks for the construction of a homochiral srs-type metal-organic framework

AU - Yang, Hui

AU - Li, Tie Hu

AU - Wang, Fei

AU - Zhang, Jian

PY - 2012/2

Y1 - 2012/2

N2 - A new homochiral metal-organic framework [ZnMg(btc)(H 2O) 4](NO 3) (1, btc = 1,3,5-benzenetricarboxylate) with unusual 3-connected heterometallic ZnMg(COO) 3 building blocks has been solvothermally synthesized and structurally characterized with the aid of single crystal X-ray diffraction. Compound 1 crystallizes in a chiral space group and exhibits 3-connected srs structural topology. The results reveal the first srs-type metal-organic framework constructed from heterometallic building blocks.

AB - A new homochiral metal-organic framework [ZnMg(btc)(H 2O) 4](NO 3) (1, btc = 1,3,5-benzenetricarboxylate) with unusual 3-connected heterometallic ZnMg(COO) 3 building blocks has been solvothermally synthesized and structurally characterized with the aid of single crystal X-ray diffraction. Compound 1 crystallizes in a chiral space group and exhibits 3-connected srs structural topology. The results reveal the first srs-type metal-organic framework constructed from heterometallic building blocks.

KW - Chiral

KW - Crystal structure

KW - Metal-organic framework

KW - Topology

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=84855715341&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2011.11.039

DO - 10.1016/j.inoche.2011.11.039

M3 - 文章

AN - SCOPUS:84855715341

SN - 1387-7003

VL - 16

SP - 86

EP - 88

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Unusual heterometallic ZnMg(COO) ₃ building blocks for the construction of a homochiral srs-type metal-organic framework

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Keywords

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