Abstract
A new three-dimensional (3D) metal-organic framework (MOF) [Cd(tpa)Cl](CH 3) 4 N + (1; tpa = 1, 4-terephthalic acid) with unusual Cd 2 (COO) 4Cl 2 building block has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) Elemental analysis (EA) and Infrared Spectroscopy (IR). The Cd 2(COO) 4Cl 2 building block can be simplified as 4-connected or two 3-connected nods in different ways, correspondingly, the compound 1 exhibits 4-connected dia or 3-connected ths structural topology.
Original language | English |
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Pages (from-to) | 30-32 |
Number of pages | 3 |
Journal | Inorganic Chemistry Communications |
Volume | 20 |
DOIs | |
State | Published - Jun 2012 |
Keywords
- Cadmium
- Crystal structure
- Metal-organic framework
- SBUs
- Topology