Two-step approach of fabrication of three-dimensional MnO2-graphene-carbon nanotube hybrid as a binder-free supercapacitor electrode

Chuanyin Xiong, Tiehu Li, Alei Dang, Tingkai Zhao, Hao Li, Huiqin Lv

Research output: Contribution to journalArticlepeer-review

152 Scopus citations

Abstract

This paper describes the fabrication and characterization of a three-dimensional (3D) MnO2-graphene (GR)-CNT hybrid obtained by combining electrochemical deposition (ELD)-electrophoretic deposition (EPD) and chemical vapor deposition (CVD). Firstly, 3D MnO2-graphene oxide (GO) is fabricated via ELD-EPD. Secondly, the catalyst and xylene are mixed with solution of certain concentration. Thirdly, catalyst is loaded on the surface of MnO2-GO when the solution is sprayed into the furnace. Forth, MnO2-GO is restored to MnO2-GR at high temperature, meanwhile, MnO2-GR is served as a substrate to grow CNT, which is beneficial to provide high speed channel for carrier and obtain pseudocapacitance of MnO2. The as-prepared hybrid is characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray Diffraction (XRD) and Raman spectroscopy (Raman), and their supercapacitor properties are also investigated. The results show that a high specific capacitance of 330.75 F g-1 and high energy density of 36.68 Wh kg-1 while maintaining high power density of 8000 W kg-1 at a scan rate of 200 mV s-1. Furthermore, the hybrid displays a high specific capacitance of 187.53 F g-1 at ultrahigh scan rate of 400 mV s-1. These attractive results demonstrate that the hybrid is a promising electrode material for high performance supercapacitors.

Original languageEnglish
Pages (from-to)602-610
Number of pages9
JournalJournal of Power Sources
Volume306
DOIs
StatePublished - 29 Feb 2016

Keywords

  • Chemical vapor deposition
  • Electrochemical deposition
  • MnO-Graphene-carbon nanotube
  • Supercapacitor
  • Three-dimensional

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