TY - JOUR
T1 - Two-step approach of fabrication of three-dimensional MnO2-graphene-carbon nanotube hybrid as a binder-free supercapacitor electrode
AU - Xiong, Chuanyin
AU - Li, Tiehu
AU - Dang, Alei
AU - Zhao, Tingkai
AU - Li, Hao
AU - Lv, Huiqin
N1 - Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.
PY - 2016/2/29
Y1 - 2016/2/29
N2 - This paper describes the fabrication and characterization of a three-dimensional (3D) MnO2-graphene (GR)-CNT hybrid obtained by combining electrochemical deposition (ELD)-electrophoretic deposition (EPD) and chemical vapor deposition (CVD). Firstly, 3D MnO2-graphene oxide (GO) is fabricated via ELD-EPD. Secondly, the catalyst and xylene are mixed with solution of certain concentration. Thirdly, catalyst is loaded on the surface of MnO2-GO when the solution is sprayed into the furnace. Forth, MnO2-GO is restored to MnO2-GR at high temperature, meanwhile, MnO2-GR is served as a substrate to grow CNT, which is beneficial to provide high speed channel for carrier and obtain pseudocapacitance of MnO2. The as-prepared hybrid is characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray Diffraction (XRD) and Raman spectroscopy (Raman), and their supercapacitor properties are also investigated. The results show that a high specific capacitance of 330.75 F g-1 and high energy density of 36.68 Wh kg-1 while maintaining high power density of 8000 W kg-1 at a scan rate of 200 mV s-1. Furthermore, the hybrid displays a high specific capacitance of 187.53 F g-1 at ultrahigh scan rate of 400 mV s-1. These attractive results demonstrate that the hybrid is a promising electrode material for high performance supercapacitors.
AB - This paper describes the fabrication and characterization of a three-dimensional (3D) MnO2-graphene (GR)-CNT hybrid obtained by combining electrochemical deposition (ELD)-electrophoretic deposition (EPD) and chemical vapor deposition (CVD). Firstly, 3D MnO2-graphene oxide (GO) is fabricated via ELD-EPD. Secondly, the catalyst and xylene are mixed with solution of certain concentration. Thirdly, catalyst is loaded on the surface of MnO2-GO when the solution is sprayed into the furnace. Forth, MnO2-GO is restored to MnO2-GR at high temperature, meanwhile, MnO2-GR is served as a substrate to grow CNT, which is beneficial to provide high speed channel for carrier and obtain pseudocapacitance of MnO2. The as-prepared hybrid is characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray Diffraction (XRD) and Raman spectroscopy (Raman), and their supercapacitor properties are also investigated. The results show that a high specific capacitance of 330.75 F g-1 and high energy density of 36.68 Wh kg-1 while maintaining high power density of 8000 W kg-1 at a scan rate of 200 mV s-1. Furthermore, the hybrid displays a high specific capacitance of 187.53 F g-1 at ultrahigh scan rate of 400 mV s-1. These attractive results demonstrate that the hybrid is a promising electrode material for high performance supercapacitors.
KW - Chemical vapor deposition
KW - Electrochemical deposition
KW - MnO-Graphene-carbon nanotube
KW - Supercapacitor
KW - Three-dimensional
UR - http://www.scopus.com/inward/record.url?scp=84958214057&partnerID=8YFLogxK
U2 - 10.1016/j.jpowsour.2015.12.056
DO - 10.1016/j.jpowsour.2015.12.056
M3 - 文章
AN - SCOPUS:84958214057
SN - 0378-7753
VL - 306
SP - 602
EP - 610
JO - Journal of Power Sources
JF - Journal of Power Sources
ER -