Two new selenidostannates with a [Sn3Se7]n2n− layer from the imidazolium-based ionic liquids: The role of (Bzmim)+ and aggregated cation of [(Emim)3Cl]2+

Zi Wang; Cheng Feng Du; Chu Chu Cheng; Nan Nan Shen; Jian Rong Li; Xiao Ying Huang

doi:10.1016/j.inoche.2016.10.040

Two new selenidostannates with a [Sn₃Se₇]_n²ⁿ⁻ layer from the imidazolium-based ionic liquids: The role of (Bzmim)⁺ and aggregated cation of [(Emim)₃Cl]²⁺

Zi Wang, Cheng Feng Du, Chu Chu Cheng, Nan Nan Shen, Jian Rong Li, Xiao Ying Huang

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Herein, we report on the syntheses, crystal structures, and optical properties of two new selenidostannates, namely, [Emim]₅[Sn₃Se₇]₂Cl (1, Emim = 1-ethyl-3-methylimidazolium) and [Bzmim]₂[Sn₃Se₇] (2, Bzmim = 1-benzyl-3-methylimidazolium). The ionic liquids (ILs) of [Emim]Cl with a short ethyl chain and [Bzmim]Cl with a bulky substituent benzyl group were used in the syntheses of compounds 1 and 2, respectively. Although both the structures feature an anionic lamellar [Sn₃Se₇]_n^2n– layer, the packing of the layers are dramatically different; such structural diversity may be ascribed to the difference of structure-directing cations incorporated in between the layers, that is [(Emim)₃Cl]²⁺ aggregates in 1 and bulky [Bzmim]⁺ in 2, respectively.

Original language	English
Pages (from-to)	58-61
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	74
DOIs	https://doi.org/10.1016/j.inoche.2016.10.040
State	Published - 1 Dec 2016
Externally published	Yes

Keywords

Aggregated cations
Crystal structure
Ionic liquids
Selenidostannate

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title = "Two new selenidostannates with a [Sn3Se7]n2n− layer from the imidazolium-based ionic liquids: The role of (Bzmim)+ and aggregated cation of [(Emim)3Cl]2+",

abstract = "Herein, we report on the syntheses, crystal structures, and optical properties of two new selenidostannates, namely, [Emim]5[Sn3Se7]2Cl (1, Emim = 1-ethyl-3-methylimidazolium) and [Bzmim]2[Sn3Se7] (2, Bzmim = 1-benzyl-3-methylimidazolium). The ionic liquids (ILs) of [Emim]Cl with a short ethyl chain and [Bzmim]Cl with a bulky substituent benzyl group were used in the syntheses of compounds 1 and 2, respectively. Although both the structures feature an anionic lamellar [Sn3Se7]n2n– layer, the packing of the layers are dramatically different; such structural diversity may be ascribed to the difference of structure-directing cations incorporated in between the layers, that is [(Emim)3Cl]2+ aggregates in 1 and bulky [Bzmim]+ in 2, respectively.",

keywords = "Aggregated cations, Crystal structure, Ionic liquids, Selenidostannate",

author = "Zi Wang and Du, {Cheng Feng} and Cheng, {Chu Chu} and Shen, {Nan Nan} and Li, {Jian Rong} and Huang, {Xiao Ying}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = dec,

day = "1",

doi = "10.1016/j.inoche.2016.10.040",

language = "英语",

volume = "74",

pages = "58--61",

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T1 - Two new selenidostannates with a [Sn3Se7]n2n− layer from the imidazolium-based ionic liquids

T2 - The role of (Bzmim)+ and aggregated cation of [(Emim)3Cl]2+

AU - Wang, Zi

AU - Du, Cheng Feng

AU - Cheng, Chu Chu

AU - Shen, Nan Nan

AU - Li, Jian Rong

AU - Huang, Xiao Ying

PY - 2016/12/1

Y1 - 2016/12/1

N2 - Herein, we report on the syntheses, crystal structures, and optical properties of two new selenidostannates, namely, [Emim]5[Sn3Se7]2Cl (1, Emim = 1-ethyl-3-methylimidazolium) and [Bzmim]2[Sn3Se7] (2, Bzmim = 1-benzyl-3-methylimidazolium). The ionic liquids (ILs) of [Emim]Cl with a short ethyl chain and [Bzmim]Cl with a bulky substituent benzyl group were used in the syntheses of compounds 1 and 2, respectively. Although both the structures feature an anionic lamellar [Sn3Se7]n2n– layer, the packing of the layers are dramatically different; such structural diversity may be ascribed to the difference of structure-directing cations incorporated in between the layers, that is [(Emim)3Cl]2+ aggregates in 1 and bulky [Bzmim]+ in 2, respectively.

AB - Herein, we report on the syntheses, crystal structures, and optical properties of two new selenidostannates, namely, [Emim]5[Sn3Se7]2Cl (1, Emim = 1-ethyl-3-methylimidazolium) and [Bzmim]2[Sn3Se7] (2, Bzmim = 1-benzyl-3-methylimidazolium). The ionic liquids (ILs) of [Emim]Cl with a short ethyl chain and [Bzmim]Cl with a bulky substituent benzyl group were used in the syntheses of compounds 1 and 2, respectively. Although both the structures feature an anionic lamellar [Sn3Se7]n2n– layer, the packing of the layers are dramatically different; such structural diversity may be ascribed to the difference of structure-directing cations incorporated in between the layers, that is [(Emim)3Cl]2+ aggregates in 1 and bulky [Bzmim]+ in 2, respectively.

KW - Aggregated cations

KW - Crystal structure

KW - Ionic liquids

KW - Selenidostannate

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U2 - 10.1016/j.inoche.2016.10.040

DO - 10.1016/j.inoche.2016.10.040

M3 - 文章

AN - SCOPUS:84994618729

SN - 1387-7003

VL - 74

SP - 58

EP - 61

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Two new selenidostannates with a [Sn₃Se₇]_n²ⁿ⁻ layer from the imidazolium-based ionic liquids: The role of (Bzmim)⁺ and aggregated cation of [(Emim)₃Cl]²⁺

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