TY - JOUR
T1 - Three-dimensional RGO/CNTs/GDY assembled microsphere
T2 - Bridging-induced electron transport enhanced microwave absorbing mechanism
AU - Ling, Mengyun
AU - Liu, Pei
AU - Wu, Fei
AU - Zhang, Baoliang
N1 - Publisher Copyright:
© 2023 Elsevier Ltd
PY - 2023/10
Y1 - 2023/10
N2 - As a new type of carbon allotrope, graphdiyne (GDY) is a promising material with highly conjugated conductive structure and excellent chemical stability. This indicates the great potential of GDY as a microwave absorbing material. Herein, we realize the simple one-step assembly of zero-dimensional GDY particles, one-dimensional carbon nanotubes (CNTs) and two-dimensional reduced graphene oxide (RGO) through ultrasonic spray method and carbonization technology, and obtained RGO/CNTs/GDY microspheres (RCG) with three-dimensional porous structure. CNTs can bridge RGO and GDY, forming a complete conductive network and providing pathways for electron migration. Benefiting from the unique three-dimensional assembly structure, high specific surface area, suitable impedance matching and strong dissipation ability, RCG shows excellent microwave absorption performance. By adjusting the assembly ratio and optimizing the filler loading, RCG-2 (RGO: CNTs: GDY = 4:1.5:1, 17.5%) with outstanding microwave absorption properties is obtained. The minimum reflection loss (RLmin) reached −51.8 dB at the matching thickness of 1.6 mm and the maximum effective absorption bandwidth (EAB) covered 5.4 GHz. The novel loss mechanism of bridge-induced electron transfer enhanced microwave absorption is proposed. It provides a new way to manufacture advanced microwave absorbers.
AB - As a new type of carbon allotrope, graphdiyne (GDY) is a promising material with highly conjugated conductive structure and excellent chemical stability. This indicates the great potential of GDY as a microwave absorbing material. Herein, we realize the simple one-step assembly of zero-dimensional GDY particles, one-dimensional carbon nanotubes (CNTs) and two-dimensional reduced graphene oxide (RGO) through ultrasonic spray method and carbonization technology, and obtained RGO/CNTs/GDY microspheres (RCG) with three-dimensional porous structure. CNTs can bridge RGO and GDY, forming a complete conductive network and providing pathways for electron migration. Benefiting from the unique three-dimensional assembly structure, high specific surface area, suitable impedance matching and strong dissipation ability, RCG shows excellent microwave absorption performance. By adjusting the assembly ratio and optimizing the filler loading, RCG-2 (RGO: CNTs: GDY = 4:1.5:1, 17.5%) with outstanding microwave absorption properties is obtained. The minimum reflection loss (RLmin) reached −51.8 dB at the matching thickness of 1.6 mm and the maximum effective absorption bandwidth (EAB) covered 5.4 GHz. The novel loss mechanism of bridge-induced electron transfer enhanced microwave absorption is proposed. It provides a new way to manufacture advanced microwave absorbers.
KW - CNTs
KW - Graphdiyne
KW - Graphene
KW - Microwave absorption
KW - Ultrasonic spray
UR - http://www.scopus.com/inward/record.url?scp=85166656362&partnerID=8YFLogxK
U2 - 10.1016/j.carbon.2023.118351
DO - 10.1016/j.carbon.2023.118351
M3 - 文章
AN - SCOPUS:85166656362
SN - 0008-6223
VL - 214
JO - Carbon
JF - Carbon
M1 - 118351
ER -