The influence of intercalation rate and degree of substitution on the electrorheological activity of a novel ternary intercalated nanocomposite

Bao Xiang Wang; Xiao Peng Zhao

doi:10.1016/j.jssc.2005.11.036

The influence of intercalation rate and degree of substitution on the electrorheological activity of a novel ternary intercalated nanocomposite

Bao Xiang Wang, Xiao Peng Zhao

School of Physical Science and Technology

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Kaolinite/dimethylsulfoxide (DMSO)/carboxymethyl starch (CMS) ternary nanocomposites were prepared according to the combination of intercalation and solution reaction. The results show that the intercalation rate (IR) of kaolinite in the ternary composite is adjusted by changing the mass rate, and the basal spacing of kaolinite was swelled from 0.715 to 1.120 nm. At the suitable component ratio of ternary nanocomposite, the optimum electrorheological (ER) effect can be attained. It is apparent that the notable ER effect of ternary ER fluid was attributed to the prominent dielectric property of the ternary nanocomposite electrorheological fluids (ERF), which is closely associated with the IR. With the increase of degree of substitution, the ER effect of ternary composite ERF is enhanced.

Original language	English
Pages (from-to)	949-954
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	179
Issue number	3
DOIs	https://doi.org/10.1016/j.jssc.2005.11.036
State	Published - Mar 2006

Keywords

Electrorheological fluid
Intercalation
Kaolinite
Nanocomposite
Ternary system

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10.1016/j.jssc.2005.11.036

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title = "The influence of intercalation rate and degree of substitution on the electrorheological activity of a novel ternary intercalated nanocomposite",

abstract = "Kaolinite/dimethylsulfoxide (DMSO)/carboxymethyl starch (CMS) ternary nanocomposites were prepared according to the combination of intercalation and solution reaction. The results show that the intercalation rate (IR) of kaolinite in the ternary composite is adjusted by changing the mass rate, and the basal spacing of kaolinite was swelled from 0.715 to 1.120 nm. At the suitable component ratio of ternary nanocomposite, the optimum electrorheological (ER) effect can be attained. It is apparent that the notable ER effect of ternary ER fluid was attributed to the prominent dielectric property of the ternary nanocomposite electrorheological fluids (ERF), which is closely associated with the IR. With the increase of degree of substitution, the ER effect of ternary composite ERF is enhanced.",

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AU - Wang, Bao Xiang

AU - Zhao, Xiao Peng

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N2 - Kaolinite/dimethylsulfoxide (DMSO)/carboxymethyl starch (CMS) ternary nanocomposites were prepared according to the combination of intercalation and solution reaction. The results show that the intercalation rate (IR) of kaolinite in the ternary composite is adjusted by changing the mass rate, and the basal spacing of kaolinite was swelled from 0.715 to 1.120 nm. At the suitable component ratio of ternary nanocomposite, the optimum electrorheological (ER) effect can be attained. It is apparent that the notable ER effect of ternary ER fluid was attributed to the prominent dielectric property of the ternary nanocomposite electrorheological fluids (ERF), which is closely associated with the IR. With the increase of degree of substitution, the ER effect of ternary composite ERF is enhanced.

AB - Kaolinite/dimethylsulfoxide (DMSO)/carboxymethyl starch (CMS) ternary nanocomposites were prepared according to the combination of intercalation and solution reaction. The results show that the intercalation rate (IR) of kaolinite in the ternary composite is adjusted by changing the mass rate, and the basal spacing of kaolinite was swelled from 0.715 to 1.120 nm. At the suitable component ratio of ternary nanocomposite, the optimum electrorheological (ER) effect can be attained. It is apparent that the notable ER effect of ternary ER fluid was attributed to the prominent dielectric property of the ternary nanocomposite electrorheological fluids (ERF), which is closely associated with the IR. With the increase of degree of substitution, the ER effect of ternary composite ERF is enhanced.

KW - Electrorheological fluid

KW - Intercalation

KW - Kaolinite

KW - Nanocomposite

KW - Ternary system

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M3 - 文章

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SN - 0022-4596

VL - 179

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The influence of intercalation rate and degree of substitution on the electrorheological activity of a novel ternary intercalated nanocomposite

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