TY - JOUR
T1 - The effect of temperature on structure and permittivity of carbon microspheres as efficient absorbent prepared by facile and large-scale method
AU - Nan, Hanyi
AU - Luo, Fa
AU - Jia, Hongyao
AU - Pan, Haijun
AU - Huang, Zhibin
AU - Deng, Hongwei
AU - Qing, Yuchang
AU - Wang, Chunhai
AU - Chen, Qiang
N1 - Publisher Copyright:
© 2021 Elsevier Ltd
PY - 2021/11/15
Y1 - 2021/11/15
N2 - Based on the concept of environment-friendly development strategy, green preparation method is crucial. Therefore, starch-derived micron solid carbon spheres (SCs) were fabricated via spray-drying followed by carbonization processing, in which is no any harmful substances in whole process. Through tuning the carbonization temperature, SCs with a moderate degree of graphitization and intrinsic defects can be obtained. The microstructure, permittivity and microwave absorption of SCs were studied. Results show that the SCs with a larger number of micropores is composed of nanocrystalline regions and amorphous areas. The paraffin-based composites with 25 wt% SCs carbonized at 800 °C displays a strong microwave loss feature, the minimum reflection loss of −64.8 dB at 9.02 GHz with thickness of 2.57 mm. Meanwhile, the effective absorption band (<-10 dB) can reach 3.1 GHz with the thickness of 2.22 mm, covering 78% of X-band, which because of its good impedance matching and dielectric loss ability resulted from the synergistic effect between the microstructure and graphitization. This work offers a facile, larger-scale and environmental-friendly method for the preparation of micron carbon-based absorbents that can serves as an alternative to nano-scale absorbents to overcome the poor dispersion of nanoparticle in the matrix.
AB - Based on the concept of environment-friendly development strategy, green preparation method is crucial. Therefore, starch-derived micron solid carbon spheres (SCs) were fabricated via spray-drying followed by carbonization processing, in which is no any harmful substances in whole process. Through tuning the carbonization temperature, SCs with a moderate degree of graphitization and intrinsic defects can be obtained. The microstructure, permittivity and microwave absorption of SCs were studied. Results show that the SCs with a larger number of micropores is composed of nanocrystalline regions and amorphous areas. The paraffin-based composites with 25 wt% SCs carbonized at 800 °C displays a strong microwave loss feature, the minimum reflection loss of −64.8 dB at 9.02 GHz with thickness of 2.57 mm. Meanwhile, the effective absorption band (<-10 dB) can reach 3.1 GHz with the thickness of 2.22 mm, covering 78% of X-band, which because of its good impedance matching and dielectric loss ability resulted from the synergistic effect between the microstructure and graphitization. This work offers a facile, larger-scale and environmental-friendly method for the preparation of micron carbon-based absorbents that can serves as an alternative to nano-scale absorbents to overcome the poor dispersion of nanoparticle in the matrix.
KW - Micron solid carbon
KW - Microstructure
KW - Microwave absorption
KW - Permittivity
UR - http://www.scopus.com/inward/record.url?scp=85116327227&partnerID=8YFLogxK
U2 - 10.1016/j.carbon.2021.09.070
DO - 10.1016/j.carbon.2021.09.070
M3 - 文章
AN - SCOPUS:85116327227
SN - 0008-6223
VL - 185
SP - 650
EP - 659
JO - Carbon
JF - Carbon
ER -