Synthesis, structural characterization and reactivity towards phenol of a bis(silyl) platinum(II) complex

Shuang Shuang Sun; Jin Fei Guo; Shi Wang; Chao Huang; Jia Yi Zhu; Yong Hua Li; Wei Huang

doi:10.1016/j.ica.2016.07.024

Synthesis, structural characterization and reactivity towards phenol of a bis(silyl) platinum(II) complex

Shuang Shuang Sun, Jin Fei Guo, Shi Wang, Chao Huang, Jia Yi Zhu, Yong Hua Li, Wei Huang

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The reaction of 1,2-C₆H₄(SiMe₂H)(SiH₃) (1) with Pt(dmpe)(PEt₃)₂(dmpe = Me₂PCH₂CH₂PMe₂) in the ratio of 1:1 yields the complex {1,2-C₆H₄(SiMe₂)(SiH₂)}Pt^II(dmpe) (2), which has unique reactivity towards sterically unhindered phenol to form an unusual diphenoxy substituted (bis)silyl platinum(II) compound (3). Only 6 examples of bis(silyl) platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.

Original language	English
Pages (from-to)	157-161
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	451
DOIs	https://doi.org/10.1016/j.ica.2016.07.024
State	Published - 2016
Externally published	Yes

Keywords

Chelating
Multinuclear NMR
Phenol
Platinum
Silyl

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title = "Synthesis, structural characterization and reactivity towards phenol of a bis(silyl) platinum(II) complex",

abstract = "The reaction of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dmpe)(PEt3)2(dmpe = Me2PCH2CH2PMe2) in the ratio of 1:1 yields the complex {1,2-C6H4(SiMe2)(SiH2)}PtII(dmpe) (2), which has unique reactivity towards sterically unhindered phenol to form an unusual diphenoxy substituted (bis)silyl platinum(II) compound (3). Only 6 examples of bis(silyl) platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.",

keywords = "Chelating, Multinuclear NMR, Phenol, Platinum, Silyl",

author = "Sun, {Shuang Shuang} and Guo, {Jin Fei} and Shi Wang and Chao Huang and Zhu, {Jia Yi} and Li, {Yong Hua} and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

doi = "10.1016/j.ica.2016.07.024",

language = "英语",

volume = "451",

pages = "157--161",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis, structural characterization and reactivity towards phenol of a bis(silyl) platinum(II) complex

AU - Sun, Shuang Shuang

AU - Guo, Jin Fei

AU - Wang, Shi

AU - Huang, Chao

AU - Zhu, Jia Yi

AU - Li, Yong Hua

AU - Huang, Wei

PY - 2016

Y1 - 2016

N2 - The reaction of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dmpe)(PEt3)2(dmpe = Me2PCH2CH2PMe2) in the ratio of 1:1 yields the complex {1,2-C6H4(SiMe2)(SiH2)}PtII(dmpe) (2), which has unique reactivity towards sterically unhindered phenol to form an unusual diphenoxy substituted (bis)silyl platinum(II) compound (3). Only 6 examples of bis(silyl) platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.

AB - The reaction of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dmpe)(PEt3)2(dmpe = Me2PCH2CH2PMe2) in the ratio of 1:1 yields the complex {1,2-C6H4(SiMe2)(SiH2)}PtII(dmpe) (2), which has unique reactivity towards sterically unhindered phenol to form an unusual diphenoxy substituted (bis)silyl platinum(II) compound (3). Only 6 examples of bis(silyl) platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.

KW - Chelating

KW - Multinuclear NMR

KW - Phenol

KW - Platinum

KW - Silyl

UR - http://www.scopus.com/inward/record.url?scp=84978727351&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2016.07.024

DO - 10.1016/j.ica.2016.07.024

M3 - 文章

AN - SCOPUS:84978727351

SN - 0020-1693

VL - 451

SP - 157

EP - 161

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Synthesis, structural characterization and reactivity towards phenol of a bis(silyl) platinum(II) complex

Abstract

Keywords

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