Synthesis, spectroscopy, and electrochemical properties of a novel p-n diblock poly(p-phenylenevinylene)-related copolymer containing bipyridine

L. H. Wang; E. T. Kang; W. Huang

doi:10.1016/S0032-3861(00)00420-1

Synthesis, spectroscopy, and electrochemical properties of a novel p-n diblock poly(p-phenylenevinylene)-related copolymer containing bipyridine

L. H. Wang, E. T. Kang, W. Huang

National University of Singapore

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A novel p-n diblock copolymer constituted of 2,2′-bipyridylene vinylene and 2-methoxy-5-(2′-ethylhexyloxy)-l,4-phenylene vinylene moieties was synthesized and characterized. The electrochemical properties of the copolymer were evaluated and the HOMO and LUMO energy levels of the polymer were estimated by cyclic voltammetry. The polymer demonstrated intrinsically balanced tendencies for injecting and transporting electrons and holes, which are essential for fabrication of light-emitting diodes.

Original language	English
Pages (from-to)	3949-3952
Number of pages	4
Journal	Polymer
Volume	42
Issue number	8
DOIs	https://doi.org/10.1016/S0032-3861(00)00420-1
State	Published - 2001
Externally published	Yes

Keywords

Bipyridine-containing copolymer
Electrochemical property
Poly(para-phenylene vinylene)

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10.1016/S0032-3861(00)00420-1

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title = "Synthesis, spectroscopy, and electrochemical properties of a novel p-n diblock poly(p-phenylenevinylene)-related copolymer containing bipyridine",

abstract = "A novel p-n diblock copolymer constituted of 2,2′-bipyridylene vinylene and 2-methoxy-5-(2′-ethylhexyloxy)-l,4-phenylene vinylene moieties was synthesized and characterized. The electrochemical properties of the copolymer were evaluated and the HOMO and LUMO energy levels of the polymer were estimated by cyclic voltammetry. The polymer demonstrated intrinsically balanced tendencies for injecting and transporting electrons and holes, which are essential for fabrication of light-emitting diodes.",

keywords = "Bipyridine-containing copolymer, Electrochemical property, Poly(para-phenylene vinylene)",

author = "Wang, {L. H.} and Kang, {E. T.} and W. Huang",

year = "2001",

doi = "10.1016/S0032-3861(00)00420-1",

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T1 - Synthesis, spectroscopy, and electrochemical properties of a novel p-n diblock poly(p-phenylenevinylene)-related copolymer containing bipyridine

AU - Wang, L. H.

AU - Kang, E. T.

AU - Huang, W.

PY - 2001

Y1 - 2001

N2 - A novel p-n diblock copolymer constituted of 2,2′-bipyridylene vinylene and 2-methoxy-5-(2′-ethylhexyloxy)-l,4-phenylene vinylene moieties was synthesized and characterized. The electrochemical properties of the copolymer were evaluated and the HOMO and LUMO energy levels of the polymer were estimated by cyclic voltammetry. The polymer demonstrated intrinsically balanced tendencies for injecting and transporting electrons and holes, which are essential for fabrication of light-emitting diodes.

AB - A novel p-n diblock copolymer constituted of 2,2′-bipyridylene vinylene and 2-methoxy-5-(2′-ethylhexyloxy)-l,4-phenylene vinylene moieties was synthesized and characterized. The electrochemical properties of the copolymer were evaluated and the HOMO and LUMO energy levels of the polymer were estimated by cyclic voltammetry. The polymer demonstrated intrinsically balanced tendencies for injecting and transporting electrons and holes, which are essential for fabrication of light-emitting diodes.

KW - Bipyridine-containing copolymer

KW - Electrochemical property

KW - Poly(para-phenylene vinylene)

UR - http://www.scopus.com/inward/record.url?scp=0034746475&partnerID=8YFLogxK

U2 - 10.1016/S0032-3861(00)00420-1

DO - 10.1016/S0032-3861(00)00420-1

M3 - 文章

AN - SCOPUS:0034746475

SN - 0032-3861

VL - 42

SP - 3949

EP - 3952

JO - Polymer

JF - Polymer

IS - 8

ER -

Synthesis, spectroscopy, and electrochemical properties of a novel p-n diblock poly(p-phenylenevinylene)-related copolymer containing bipyridine

Abstract

Keywords

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