Synthesis and luminescent properties of lanthanide-doped ScVO4 microcrystals

Shuilin XU; Xiaoji XIE; Baozhou ZHAO; Li NIE; Yue PAN; Haiquan SU; Ling HUANG; Wei HUANG

doi:10.1016/S1002-0721(16)60169-2

Synthesis and luminescent properties of lanthanide-doped ScVO₄ microcrystals

Shuilin XU, Xiaoji XIE, Baozhou ZHAO, Li NIE, Yue PAN, Haiquan SU, Ling HUANG, Wei HUANG

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

High quality and monodispersed ScVO₄ microcrystals were successfully synthesized via a mild hydrothermal route using NH₄VO₃ as vanadium source. The X-ray power diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) results indicated that the size, shape, and phase formation of the ScVO₄ microcrystals could be tuned by altering the reaction temperature, reaction time, and pH value of the initial solution. Furthermore, the down- and upconversion luminescence of ScVO₄:Ln (Ln=Eu, Dy, Sm, Yb/Ho, Yb/Er, and Yb/Tm) microcrystals were characterized and the respective energy transfer processes were also discussed. The experimental results demonstrated that reactions at 200 °C, 24 h, and pH=6 could generate perfect ScVO₄ microcrystals, which were then used for luminescence studies.

Original language	English
Pages (from-to)	28-33
Number of pages	6
Journal	Journal of Rare Earths
Volume	35
Issue number	1
DOIs	https://doi.org/10.1016/S1002-0721(16)60169-2
State	Published - 1 Jan 2017
Externally published	Yes

Keywords

down/upconversion luminescence
hydrothermal synthesis
rare earths
ScVO

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10.1016/S1002-0721(16)60169-2

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title = "Synthesis and luminescent properties of lanthanide-doped ScVO4 microcrystals",

abstract = "High quality and monodispersed ScVO4 microcrystals were successfully synthesized via a mild hydrothermal route using NH4VO3 as vanadium source. The X-ray power diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) results indicated that the size, shape, and phase formation of the ScVO4 microcrystals could be tuned by altering the reaction temperature, reaction time, and pH value of the initial solution. Furthermore, the down- and upconversion luminescence of ScVO4:Ln (Ln=Eu, Dy, Sm, Yb/Ho, Yb/Er, and Yb/Tm) microcrystals were characterized and the respective energy transfer processes were also discussed. The experimental results demonstrated that reactions at 200 °C, 24 h, and pH=6 could generate perfect ScVO4 microcrystals, which were then used for luminescence studies.",

keywords = "down/upconversion luminescence, hydrothermal synthesis, rare earths, ScVO",

author = "Shuilin XU and Xiaoji XIE and Baozhou ZHAO and Li NIE and Yue PAN and Haiquan SU and Ling HUANG and Wei HUANG",

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doi = "10.1016/S1002-0721(16)60169-2",

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T1 - Synthesis and luminescent properties of lanthanide-doped ScVO4 microcrystals

AU - XU, Shuilin

AU - XIE, Xiaoji

AU - ZHAO, Baozhou

AU - NIE, Li

AU - PAN, Yue

AU - SU, Haiquan

AU - HUANG, Ling

AU - HUANG, Wei

PY - 2017/1/1

Y1 - 2017/1/1

N2 - High quality and monodispersed ScVO4 microcrystals were successfully synthesized via a mild hydrothermal route using NH4VO3 as vanadium source. The X-ray power diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) results indicated that the size, shape, and phase formation of the ScVO4 microcrystals could be tuned by altering the reaction temperature, reaction time, and pH value of the initial solution. Furthermore, the down- and upconversion luminescence of ScVO4:Ln (Ln=Eu, Dy, Sm, Yb/Ho, Yb/Er, and Yb/Tm) microcrystals were characterized and the respective energy transfer processes were also discussed. The experimental results demonstrated that reactions at 200 °C, 24 h, and pH=6 could generate perfect ScVO4 microcrystals, which were then used for luminescence studies.

AB - High quality and monodispersed ScVO4 microcrystals were successfully synthesized via a mild hydrothermal route using NH4VO3 as vanadium source. The X-ray power diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) results indicated that the size, shape, and phase formation of the ScVO4 microcrystals could be tuned by altering the reaction temperature, reaction time, and pH value of the initial solution. Furthermore, the down- and upconversion luminescence of ScVO4:Ln (Ln=Eu, Dy, Sm, Yb/Ho, Yb/Er, and Yb/Tm) microcrystals were characterized and the respective energy transfer processes were also discussed. The experimental results demonstrated that reactions at 200 °C, 24 h, and pH=6 could generate perfect ScVO4 microcrystals, which were then used for luminescence studies.

KW - down/upconversion luminescence

KW - hydrothermal synthesis

KW - rare earths

KW - ScVO

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DO - 10.1016/S1002-0721(16)60169-2

M3 - 文章

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SN - 1002-0721

VL - 35

SP - 28

EP - 33

JO - Journal of Rare Earths

JF - Journal of Rare Earths

IS - 1

ER -

Synthesis and luminescent properties of lanthanide-doped ScVO₄ microcrystals

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Keywords

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