Synthesis and characterization of a novel poly(p-phenylenevinylene) derivative carrying an oxadiazole side chain with improved electron affinity

Nancy Hoi Sim Lee; Zhi Kuan Chen; Soo Jin Chua; Yee Hing Lai; Wei Huang

doi:10.1016/S0040-6090(99)01034-2

Synthesis and characterization of a novel poly(p-phenylenevinylene) derivative carrying an oxadiazole side chain with improved electron affinity

Nancy Hoi Sim Lee, Zhi Kuan Chen, Soo Jin Chua, Yee Hing Lai, Wei Huang

National University of Singapore

Research output: Contribution to journal › Conference article › peer-review

13 Scopus citations

Abstract

Electroluminescent conjugated polymers based on poly(p-phenylenevinylene) (PPV) have been a subject of interest due to their potential application in light-emitting devices (LEDs). Here an oxadiazole-containing PPV polymer, poly[2-(5′-nonyl-1′,3′,4′-oxadiazole-2′-yl)-1,4- phenylenevinylene)], was synthesized through the Gilch route. The 1,3,4-oxadiazole unit was introduced as a side-chain into the PPV system to improve the electron affinity of the polymer. The electrochemical investigation of the polymer indicates that the polymer electron affinity has been significantly enhanced, which can be comparable to CN-PPV. The polymer and its intermediates have been characterized by various techniques such as FTIR, MS and NMR.

Original language	English
Pages (from-to)	106-109
Number of pages	4
Journal	Thin Solid Films
Volume	363
Issue number	1
DOIs	https://doi.org/10.1016/S0040-6090(99)01034-2
State	Published - 1 Mar 2000
Externally published	Yes
Event	The Asia-Pacific Symposium on Organic Electroluminescent Materials and Devices - Hong Kong, Hong Kong Duration: 8 Jun 1999 → 11 Jun 1999

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title = "Synthesis and characterization of a novel poly(p-phenylenevinylene) derivative carrying an oxadiazole side chain with improved electron affinity",

abstract = "Electroluminescent conjugated polymers based on poly(p-phenylenevinylene) (PPV) have been a subject of interest due to their potential application in light-emitting devices (LEDs). Here an oxadiazole-containing PPV polymer, poly[2-(5′-nonyl-1′,3′,4′-oxadiazole-2′-yl)-1,4- phenylenevinylene)], was synthesized through the Gilch route. The 1,3,4-oxadiazole unit was introduced as a side-chain into the PPV system to improve the electron affinity of the polymer. The electrochemical investigation of the polymer indicates that the polymer electron affinity has been significantly enhanced, which can be comparable to CN-PPV. The polymer and its intermediates have been characterized by various techniques such as FTIR, MS and NMR.",

author = "Lee, {Nancy Hoi Sim} and Chen, {Zhi Kuan} and Chua, {Soo Jin} and Lai, {Yee Hing} and Wei Huang",

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doi = "10.1016/S0040-6090(99)01034-2",

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note = "The Asia-Pacific Symposium on Organic Electroluminescent Materials and Devices ; Conference date: 08-06-1999 Through 11-06-1999",

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T1 - Synthesis and characterization of a novel poly(p-phenylenevinylene) derivative carrying an oxadiazole side chain with improved electron affinity

AU - Lee, Nancy Hoi Sim

AU - Chen, Zhi Kuan

AU - Chua, Soo Jin

AU - Lai, Yee Hing

AU - Huang, Wei

PY - 2000/3/1

Y1 - 2000/3/1

N2 - Electroluminescent conjugated polymers based on poly(p-phenylenevinylene) (PPV) have been a subject of interest due to their potential application in light-emitting devices (LEDs). Here an oxadiazole-containing PPV polymer, poly[2-(5′-nonyl-1′,3′,4′-oxadiazole-2′-yl)-1,4- phenylenevinylene)], was synthesized through the Gilch route. The 1,3,4-oxadiazole unit was introduced as a side-chain into the PPV system to improve the electron affinity of the polymer. The electrochemical investigation of the polymer indicates that the polymer electron affinity has been significantly enhanced, which can be comparable to CN-PPV. The polymer and its intermediates have been characterized by various techniques such as FTIR, MS and NMR.

AB - Electroluminescent conjugated polymers based on poly(p-phenylenevinylene) (PPV) have been a subject of interest due to their potential application in light-emitting devices (LEDs). Here an oxadiazole-containing PPV polymer, poly[2-(5′-nonyl-1′,3′,4′-oxadiazole-2′-yl)-1,4- phenylenevinylene)], was synthesized through the Gilch route. The 1,3,4-oxadiazole unit was introduced as a side-chain into the PPV system to improve the electron affinity of the polymer. The electrochemical investigation of the polymer indicates that the polymer electron affinity has been significantly enhanced, which can be comparable to CN-PPV. The polymer and its intermediates have been characterized by various techniques such as FTIR, MS and NMR.

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U2 - 10.1016/S0040-6090(99)01034-2

DO - 10.1016/S0040-6090(99)01034-2

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SN - 0040-6090

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EP - 109

JO - Thin Solid Films

JF - Thin Solid Films

IS - 1

T2 - The Asia-Pacific Symposium on Organic Electroluminescent Materials and Devices

Y2 - 8 June 1999 through 11 June 1999

ER -

Synthesis and characterization of a novel poly(p-phenylenevinylene) derivative carrying an oxadiazole side chain with improved electron affinity

Abstract

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