Study on the synthesis and properties of condensed polynuclear aromatics resin using coal tar pitch as monomer and p-methyl benzaldehyde as cross-linking agent

Qi Lang Lin; Tie Hu Li

Study on the synthesis and properties of condensed polynuclear aromatics resin using coal tar pitch as monomer and p-methyl benzaldehyde as cross-linking agent

Qi Lang Lin, Tie Hu Li

School of Materials Sience and Engineering

Fuzhou University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The condensed polynuclear aromatic (COPNA) resin is synthesized using coal tar pitch as monomer and p-methyl benzaldehyde (PMB) as cross-linking agent in the presence of p-toluene sulfonic acid. Reaction mechanism was studied using FT-IR and ¹H-NMR. The morphologies of COPNA resin were inspected by SEM. TG-DSC was employed to study the thermal behavior of COPNA resin. The results show that coal tar pitch and PMB can be used to synthesize COPNA resin, the reaction mechanism of which is a positive ion-typed condensation polymerization catalyzed by acid. There exist many micro fibers with a uniform distribution in the COPNA resin. The fibers grow with increase of modification time, and then intertwist and amalgamate. Moreover, the COPNA resin possesses good thermo-stability and high coke value.

Original language	English
Pages (from-to)	102-104+108
Journal	Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering
Volume	22
Issue number	5
State	Published - Sep 2006

Keywords

Coal tar pitch
COPNA
PMB
Properties
Synthesis

Cite this

@article{f729fb755cd34a2da3d756ed8d1d87fd,

title = "Study on the synthesis and properties of condensed polynuclear aromatics resin using coal tar pitch as monomer and p-methyl benzaldehyde as cross-linking agent",

abstract = "The condensed polynuclear aromatic (COPNA) resin is synthesized using coal tar pitch as monomer and p-methyl benzaldehyde (PMB) as cross-linking agent in the presence of p-toluene sulfonic acid. Reaction mechanism was studied using FT-IR and 1H-NMR. The morphologies of COPNA resin were inspected by SEM. TG-DSC was employed to study the thermal behavior of COPNA resin. The results show that coal tar pitch and PMB can be used to synthesize COPNA resin, the reaction mechanism of which is a positive ion-typed condensation polymerization catalyzed by acid. There exist many micro fibers with a uniform distribution in the COPNA resin. The fibers grow with increase of modification time, and then intertwist and amalgamate. Moreover, the COPNA resin possesses good thermo-stability and high coke value.",

keywords = "Coal tar pitch, COPNA, PMB, Properties, Synthesis",

author = "Lin, {Qi Lang} and Li, {Tie Hu}",

year = "2006",

month = sep,

language = "英语",

volume = "22",

pages = "102--104+108",

journal = "Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering",

issn = "1000-7555",

publisher = "Chengdu University of Science and Technology",

number = "5",

}

Study on the synthesis and properties of condensed polynuclear aromatics resin using coal tar pitch as monomer and p-methyl benzaldehyde as cross-linking agent. / Lin, Qi Lang; Li, Tie Hu.
In: Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, Vol. 22, No. 5, 09.2006, p. 102-104+108.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Study on the synthesis and properties of condensed polynuclear aromatics resin using coal tar pitch as monomer and p-methyl benzaldehyde as cross-linking agent

AU - Lin, Qi Lang

AU - Li, Tie Hu

PY - 2006/9

Y1 - 2006/9

N2 - The condensed polynuclear aromatic (COPNA) resin is synthesized using coal tar pitch as monomer and p-methyl benzaldehyde (PMB) as cross-linking agent in the presence of p-toluene sulfonic acid. Reaction mechanism was studied using FT-IR and 1H-NMR. The morphologies of COPNA resin were inspected by SEM. TG-DSC was employed to study the thermal behavior of COPNA resin. The results show that coal tar pitch and PMB can be used to synthesize COPNA resin, the reaction mechanism of which is a positive ion-typed condensation polymerization catalyzed by acid. There exist many micro fibers with a uniform distribution in the COPNA resin. The fibers grow with increase of modification time, and then intertwist and amalgamate. Moreover, the COPNA resin possesses good thermo-stability and high coke value.

AB - The condensed polynuclear aromatic (COPNA) resin is synthesized using coal tar pitch as monomer and p-methyl benzaldehyde (PMB) as cross-linking agent in the presence of p-toluene sulfonic acid. Reaction mechanism was studied using FT-IR and 1H-NMR. The morphologies of COPNA resin were inspected by SEM. TG-DSC was employed to study the thermal behavior of COPNA resin. The results show that coal tar pitch and PMB can be used to synthesize COPNA resin, the reaction mechanism of which is a positive ion-typed condensation polymerization catalyzed by acid. There exist many micro fibers with a uniform distribution in the COPNA resin. The fibers grow with increase of modification time, and then intertwist and amalgamate. Moreover, the COPNA resin possesses good thermo-stability and high coke value.

KW - Coal tar pitch

KW - COPNA

KW - PMB

KW - Properties

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=33845516053&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:33845516053

SN - 1000-7555

VL - 22

SP - 102-104+108

JO - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

JF - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

IS - 5

ER -

Study on the synthesis and properties of condensed polynuclear aromatics resin using coal tar pitch as monomer and p-methyl benzaldehyde as cross-linking agent

Abstract

Keywords

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