Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane

Zhenhuan Pan; Minglun Liu; Chaoyue Zheng; Deqing Gao; Wei Huang

doi:10.1002/cjoc.201700024

Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane

Zhenhuan Pan, Minglun Liu, Chaoyue Zheng, Deqing Gao, Wei Huang

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Pt_n(H₂C=CHSiMe₂OSiMe₂CH=CH₂)_m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.

Original language	English
Pages (from-to)	1227-1230
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	35
Issue number	8
DOIs	https://doi.org/10.1002/cjoc.201700024
State	Published - 1 Aug 2017
Externally published	Yes

Keywords

Karstedt's catalyst
aminated alkenes
hydrosilylation
selectivity

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10.1002/cjoc.201700024

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title = "Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane",

abstract = "The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Ptn(H2C=CHSiMe2OSiMe2CH=CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.",

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T1 - Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane

AU - Pan, Zhenhuan

AU - Liu, Minglun

AU - Zheng, Chaoyue

AU - Gao, Deqing

AU - Huang, Wei

PY - 2017/8/1

Y1 - 2017/8/1

N2 - The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Ptn(H2C=CHSiMe2OSiMe2CH=CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.

AB - The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Ptn(H2C=CHSiMe2OSiMe2CH=CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.

KW - Karstedt's catalyst

KW - aminated alkenes

KW - hydrosilylation

KW - selectivity

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M3 - 文章

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SN - 1001-604X

VL - 35

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EP - 1230

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 8

ER -

Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane

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Keywords

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