TY - JOUR
T1 - Structural modification and phase transformation kinetics
T2 - Crystallization of amorphous Fe40Ni40P14B6 eutectic alloy
AU - Gu, Bin
AU - Liu, Feng
AU - Chen, Yu Zeng
AU - Jiang, Yi Hui
AU - Ma, Ya Zhu
PY - 2014/1
Y1 - 2014/1
N2 - The effect of processing histories (fluxing and pre-annealing) on the amorphous structure and the crystallization kinetics of amorphous Fe 40Ni40P14B6 alloy prepared by melt spinning has been studied by differential scanning calorimetry, X-ray diffraction, transmission and scanning electron microscopy. For isothermal crystallization, an incubation time exists, and for isochronal crystallization, an abnormally sharp crystallization peak (with the transformed fraction corresponding to the transformation-rate maximum f p as less than 0.632) occurs. Subjected to fluxing and pre-annealing, the incubation time (in isothermal crystallization) decreases, whereas the initial crystallization temperature (in isochronal crystallization) declines as well as the less sharp crystallization peak and f p approaches 0.632. A kinetic model considering transient nucleation is proposed and analyzed, which could describe well the singular crystallization behavior of amorphous Fe40Ni 40P14B6 alloy. A recipe based on the kinetic model is also proposed to obtain the kinetic parameters from experiment data. Via kinetic analysis and amorphous structural characterization, it is considered that pre-annealing and fluxing promote relaxation of the system close to the meta-stable equilibrium state; the atomic structure becomes more similar to the correspondingly crystallized phase, thus declining the amorphous stability and alleviating the transient effect on nucleation.
AB - The effect of processing histories (fluxing and pre-annealing) on the amorphous structure and the crystallization kinetics of amorphous Fe 40Ni40P14B6 alloy prepared by melt spinning has been studied by differential scanning calorimetry, X-ray diffraction, transmission and scanning electron microscopy. For isothermal crystallization, an incubation time exists, and for isochronal crystallization, an abnormally sharp crystallization peak (with the transformed fraction corresponding to the transformation-rate maximum f p as less than 0.632) occurs. Subjected to fluxing and pre-annealing, the incubation time (in isothermal crystallization) decreases, whereas the initial crystallization temperature (in isochronal crystallization) declines as well as the less sharp crystallization peak and f p approaches 0.632. A kinetic model considering transient nucleation is proposed and analyzed, which could describe well the singular crystallization behavior of amorphous Fe40Ni 40P14B6 alloy. A recipe based on the kinetic model is also proposed to obtain the kinetic parameters from experiment data. Via kinetic analysis and amorphous structural characterization, it is considered that pre-annealing and fluxing promote relaxation of the system close to the meta-stable equilibrium state; the atomic structure becomes more similar to the correspondingly crystallized phase, thus declining the amorphous stability and alleviating the transient effect on nucleation.
UR - http://www.scopus.com/inward/record.url?scp=84891387120&partnerID=8YFLogxK
U2 - 10.1007/s10853-013-7768-9
DO - 10.1007/s10853-013-7768-9
M3 - 文章
AN - SCOPUS:84891387120
SN - 0022-2461
VL - 49
SP - 842
EP - 857
JO - Journal of Materials Science
JF - Journal of Materials Science
IS - 2
ER -