Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20N60 and Na24N60 Nanocages

Wenquan Zhang; Kangcai Wang; Juecheng Li; Zhien Lin; Siwei Song; Shiliang Huang; Yu Liu; Fude Nie; Qinghua Zhang

doi:10.1002/anie.201710602

Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na₂₀N₆₀ and Na₂₄N₆₀ Nanocages

Wenquan Zhang, Kangcai Wang, Juecheng Li, Zhien Lin, Siwei Song, Shiliang Huang, Yu Liu, Fude Nie, Qinghua Zhang

Research output: Contribution to journal › Article › peer-review

119 Scopus citations

Abstract

The experimental detection and synthesis of pentazole (HN₅) and its anion (cyclo-N₅⁻) have been actively pursued for the past hundred years. The synthesis of an aesthetic three-dimensional metal–pentazolate framework (denoted as MPF-1) is presented. It consists of sodium ions and cyclo-N₅⁻ anions in which the isolated cyclo-N₅⁻ anions are preternaturally stabilized in this inorganic open framework featuring two types of nanocages (Na₂₀N₆₀ and Na₂₄N₆₀) through strong metal coordination bonds. The compound MPF-1 is indefinitely stable at room temperature and exhibits high thermal stability relative to the reported cyclo-N₅⁻ salts. This finding offers a new approach to create metal–pentazolate frameworks (MPFs) and enables the future exploration of interesting pentazole chemistry and also related functional materials.

Original language	English
Pages (from-to)	2592-2595
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	10
DOIs	https://doi.org/10.1002/anie.201710602
State	Published - 1 Mar 2018
Externally published	Yes

Keywords

nanocages
pentazole
stabilization
thermal stability
zeolitic frameworks

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title = "Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20N60 and Na24N60 Nanocages",

abstract = "The experimental detection and synthesis of pentazole (HN5) and its anion (cyclo-N5−) have been actively pursued for the past hundred years. The synthesis of an aesthetic three-dimensional metal–pentazolate framework (denoted as MPF-1) is presented. It consists of sodium ions and cyclo-N5− anions in which the isolated cyclo-N5− anions are preternaturally stabilized in this inorganic open framework featuring two types of nanocages (Na20N60 and Na24N60) through strong metal coordination bonds. The compound MPF-1 is indefinitely stable at room temperature and exhibits high thermal stability relative to the reported cyclo-N5− salts. This finding offers a new approach to create metal–pentazolate frameworks (MPFs) and enables the future exploration of interesting pentazole chemistry and also related functional materials.",

keywords = "nanocages, pentazole, stabilization, thermal stability, zeolitic frameworks",

author = "Wenquan Zhang and Kangcai Wang and Juecheng Li and Zhien Lin and Siwei Song and Shiliang Huang and Yu Liu and Fude Nie and Qinghua Zhang",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2018",

month = mar,

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doi = "10.1002/anie.201710602",

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T1 - Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20N60 and Na24N60 Nanocages

AU - Zhang, Wenquan

AU - Wang, Kangcai

AU - Li, Juecheng

AU - Lin, Zhien

AU - Song, Siwei

AU - Huang, Shiliang

AU - Liu, Yu

AU - Nie, Fude

AU - Zhang, Qinghua

PY - 2018/3/1

Y1 - 2018/3/1

N2 - The experimental detection and synthesis of pentazole (HN5) and its anion (cyclo-N5−) have been actively pursued for the past hundred years. The synthesis of an aesthetic three-dimensional metal–pentazolate framework (denoted as MPF-1) is presented. It consists of sodium ions and cyclo-N5− anions in which the isolated cyclo-N5− anions are preternaturally stabilized in this inorganic open framework featuring two types of nanocages (Na20N60 and Na24N60) through strong metal coordination bonds. The compound MPF-1 is indefinitely stable at room temperature and exhibits high thermal stability relative to the reported cyclo-N5− salts. This finding offers a new approach to create metal–pentazolate frameworks (MPFs) and enables the future exploration of interesting pentazole chemistry and also related functional materials.

AB - The experimental detection and synthesis of pentazole (HN5) and its anion (cyclo-N5−) have been actively pursued for the past hundred years. The synthesis of an aesthetic three-dimensional metal–pentazolate framework (denoted as MPF-1) is presented. It consists of sodium ions and cyclo-N5− anions in which the isolated cyclo-N5− anions are preternaturally stabilized in this inorganic open framework featuring two types of nanocages (Na20N60 and Na24N60) through strong metal coordination bonds. The compound MPF-1 is indefinitely stable at room temperature and exhibits high thermal stability relative to the reported cyclo-N5− salts. This finding offers a new approach to create metal–pentazolate frameworks (MPFs) and enables the future exploration of interesting pentazole chemistry and also related functional materials.

KW - nanocages

KW - pentazole

KW - stabilization

KW - thermal stability

KW - zeolitic frameworks

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AN - SCOPUS:85041322660

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JO - Angewandte Chemie - International Edition

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IS - 10

ER -

Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na₂₀N₆₀ and Na₂₄N₆₀ Nanocages

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Keywords

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