Spirocyclic aromatic hydrocarbons (SAHs) and their synthetic methodologies

Ling Hai Xie; Jing Liang; Juan Song; Cheng Rong Yin; Wei Huang

doi:10.2174/138527210793351599

Spirocyclic aromatic hydrocarbons (SAHs) and their synthetic methodologies

Ling Hai Xie, Jing Liang, Juan Song, Cheng Rong Yin, Wei Huang

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

Spirocyclic aromatic hydrocarbons (SAHs) or spirocyclic arenes are functional building blocks in constructing amorphous organic/ polymeric semiconductors with high glass transition temperatures for organic electronic devices. In this review, SAHs were categorized into three classes - mono-spirocyclic aromatic hydrocarbons (MSAHs), heteroatom-containing spirocyclic aromatic hydrocarbons (HSAHs), and polyspirocyclic aromatic hydrocarbons (PSAHs) based on MSAHs and HSAHs. Various synthetic strategies of SAHs, viz., o-halobiaryl method, diarylfluorene method, dibiarylketone method, one-pot domino synthesis, tandem dilithiation method, alkyne-fused aromatization, allene method, and other related routes were summarized.

Original language	English
Pages (from-to)	2169-2195
Number of pages	27
Journal	Current Organic Chemistry
Volume	14
Issue number	18
DOIs	https://doi.org/10.2174/138527210793351599
State	Published - 2010
Externally published	Yes

Keywords

Cruciform π-system
Light-emitting materials
O-halobiaryls
Organic semiconductors
Spiro-compounds
Spirobifluorene

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abstract = "Spirocyclic aromatic hydrocarbons (SAHs) or spirocyclic arenes are functional building blocks in constructing amorphous organic/ polymeric semiconductors with high glass transition temperatures for organic electronic devices. In this review, SAHs were categorized into three classes - mono-spirocyclic aromatic hydrocarbons (MSAHs), heteroatom-containing spirocyclic aromatic hydrocarbons (HSAHs), and polyspirocyclic aromatic hydrocarbons (PSAHs) based on MSAHs and HSAHs. Various synthetic strategies of SAHs, viz., o-halobiaryl method, diarylfluorene method, dibiarylketone method, one-pot domino synthesis, tandem dilithiation method, alkyne-fused aromatization, allene method, and other related routes were summarized.",

keywords = "Cruciform π-system, Light-emitting materials, O-halobiaryls, Organic semiconductors, Spiro-compounds, Spirobifluorene",

author = "Xie, {Ling Hai} and Jing Liang and Juan Song and Yin, {Cheng Rong} and Wei Huang",

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doi = "10.2174/138527210793351599",

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AU - Xie, Ling Hai

AU - Liang, Jing

AU - Song, Juan

AU - Yin, Cheng Rong

AU - Huang, Wei

PY - 2010

Y1 - 2010

N2 - Spirocyclic aromatic hydrocarbons (SAHs) or spirocyclic arenes are functional building blocks in constructing amorphous organic/ polymeric semiconductors with high glass transition temperatures for organic electronic devices. In this review, SAHs were categorized into three classes - mono-spirocyclic aromatic hydrocarbons (MSAHs), heteroatom-containing spirocyclic aromatic hydrocarbons (HSAHs), and polyspirocyclic aromatic hydrocarbons (PSAHs) based on MSAHs and HSAHs. Various synthetic strategies of SAHs, viz., o-halobiaryl method, diarylfluorene method, dibiarylketone method, one-pot domino synthesis, tandem dilithiation method, alkyne-fused aromatization, allene method, and other related routes were summarized.

AB - Spirocyclic aromatic hydrocarbons (SAHs) or spirocyclic arenes are functional building blocks in constructing amorphous organic/ polymeric semiconductors with high glass transition temperatures for organic electronic devices. In this review, SAHs were categorized into three classes - mono-spirocyclic aromatic hydrocarbons (MSAHs), heteroatom-containing spirocyclic aromatic hydrocarbons (HSAHs), and polyspirocyclic aromatic hydrocarbons (PSAHs) based on MSAHs and HSAHs. Various synthetic strategies of SAHs, viz., o-halobiaryl method, diarylfluorene method, dibiarylketone method, one-pot domino synthesis, tandem dilithiation method, alkyne-fused aromatization, allene method, and other related routes were summarized.

KW - Cruciform π-system

KW - Light-emitting materials

KW - O-halobiaryls

KW - Organic semiconductors

KW - Spiro-compounds

KW - Spirobifluorene

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DO - 10.2174/138527210793351599

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Spirocyclic aromatic hydrocarbons (SAHs) and their synthetic methodologies

Abstract

Keywords

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