Self-healable transparent polymer/salt hybrid adhesive: Via a ternary bonding effect

Yuanyuan Zhang, Ke Zhang, Xuanhua Li, Tong Li, Qian Ye, Li Li Tan, Bingqing Wei

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

Tremendous attention has been focused on the design and fabrication of intrinsic self-healing materials in recent years; however, the fabrication of self-healing materials with high transparency and high adhesion strength is still a challenge. Here, we develop a novel transparent self-healing adhesive with multiple functions by simply blending poly(2-ethyl-2-oxazoline) (PEOZ), poly(4-hydroxy styrene) (PHS), and CaCl2, and discover that the anion Cl- also plays a significant role in accelerating the self-healing process by anion-ligand coordination in the form of hydrogen bonding, which has been seriously neglected in previous work. Unlike the common single metal-ligand coordination approach, the enhancement of self-healing results from novel co-existing ternary bridging bonds: metal-ligand coordination, ionic bond, and anion coordination. The universality of the new concept has been verified with other typical soluble salts MgCl2, NaCl, and Ca(NO3)2, providing a new dimension in the comprehension of the self-healing mechanisms. As a result, the hybrid shows outstanding multifunctional performance compared with the most recently published self-healable adhesives taking into consideration the transparency (T550 = 98.9%), adhesion strength (2.57 MPa), and self-healing efficiency (91%), enabling its application as an optical material, an adhesive and also a conservation material for cultural heritage.

Original languageEnglish
Pages (from-to)21812-21823
Number of pages12
JournalJournal of Materials Chemistry A
Volume8
Issue number41
DOIs
StatePublished - 7 Nov 2020

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