Scalable synthesis of high-energy–density fuels via highly-integrated domino annulation of biomass derived ketenes

Bo Yang; Haowen Xing; Jun Zhang; Xiumei Ma; Qiuyu Zhang; Ji Jun Zou; Junjian Xie

doi:10.1016/j.fuel.2025.134566

Scalable synthesis of high-energy–density fuels via highly-integrated domino annulation of biomass derived ketenes

Bo Yang, Haowen Xing, Jun Zhang, Xiumei Ma, Qiuyu Zhang, Ji Jun Zou, Junjian Xie

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Renewable jet-fuel-ranged fused-ring fuel is first synthesized at the kilogram level via highly-integrated domino annulation of isophorone, which owns much higher density (0.918 g/mL), higher neat heat of combustion (42.85 MJ/kg) and lower freezing point (−52 °C) than other biofuels synthesized from isophorone, and thus illustrates a new type of high-quality biofuels appealing for practical applications.

Original language	English
Article number	134566
Journal	Fuel
Volume	389
DOIs	https://doi.org/10.1016/j.fuel.2025.134566
State	Published - 1 Jun 2025

Keywords

Biofuel
Biomass-based isophorone
Domino annulation
High-density fuel
Hydrodeoxygenation

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.fuel.2025.134566

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title = "Scalable synthesis of high-energy–density fuels via highly-integrated domino annulation of biomass derived ketenes",

abstract = "Renewable jet-fuel-ranged fused-ring fuel is first synthesized at the kilogram level via highly-integrated domino annulation of isophorone, which owns much higher density (0.918 g/mL), higher neat heat of combustion (42.85 MJ/kg) and lower freezing point (−52 °C) than other biofuels synthesized from isophorone, and thus illustrates a new type of high-quality biofuels appealing for practical applications.",

keywords = "Biofuel, Biomass-based isophorone, Domino annulation, High-density fuel, Hydrodeoxygenation",

author = "Bo Yang and Haowen Xing and Jun Zhang and Xiumei Ma and Qiuyu Zhang and Zou, {Ji Jun} and Junjian Xie",

note = "Publisher Copyright: {\textcopyright} 2025 Elsevier Ltd",

year = "2025",

month = jun,

day = "1",

doi = "10.1016/j.fuel.2025.134566",

language = "英语",

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journal = "Fuel",

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T1 - Scalable synthesis of high-energy–density fuels via highly-integrated domino annulation of biomass derived ketenes

AU - Yang, Bo

AU - Xing, Haowen

AU - Zhang, Jun

AU - Ma, Xiumei

AU - Zhang, Qiuyu

AU - Zou, Ji Jun

AU - Xie, Junjian

PY - 2025/6/1

Y1 - 2025/6/1

N2 - Renewable jet-fuel-ranged fused-ring fuel is first synthesized at the kilogram level via highly-integrated domino annulation of isophorone, which owns much higher density (0.918 g/mL), higher neat heat of combustion (42.85 MJ/kg) and lower freezing point (−52 °C) than other biofuels synthesized from isophorone, and thus illustrates a new type of high-quality biofuels appealing for practical applications.

AB - Renewable jet-fuel-ranged fused-ring fuel is first synthesized at the kilogram level via highly-integrated domino annulation of isophorone, which owns much higher density (0.918 g/mL), higher neat heat of combustion (42.85 MJ/kg) and lower freezing point (−52 °C) than other biofuels synthesized from isophorone, and thus illustrates a new type of high-quality biofuels appealing for practical applications.

KW - Biofuel

KW - Biomass-based isophorone

KW - Domino annulation

KW - High-density fuel

KW - Hydrodeoxygenation

UR - http://www.scopus.com/inward/record.url?scp=85216931671&partnerID=8YFLogxK

U2 - 10.1016/j.fuel.2025.134566

DO - 10.1016/j.fuel.2025.134566

M3 - 文章

AN - SCOPUS:85216931671

SN - 0016-2361

VL - 389

JO - Fuel

JF - Fuel

M1 - 134566

ER -

Scalable synthesis of high-energy–density fuels via highly-integrated domino annulation of biomass derived ketenes

Abstract

Keywords

UN SDGs

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