Promoting hole transfer for photoelectrochemical water oxidation through a manganese cluster catalyst bioinspired by natural photosystem II

Bin Gao; Tao Wang; Yang Li; Xiaoli Fan; Hao Gong; Cheng Jiang; Peng Li; Xianli Huang; Jianping He

doi:10.1039/d0cc00955e

Promoting hole transfer for photoelectrochemical water oxidation through a manganese cluster catalyst bioinspired by natural photosystem II

Bin Gao, Tao Wang, Yang Li, Xiaoli Fan, Hao Gong, Cheng Jiang, Peng Li, Xianli Huang, Jianping He

Nanjing University of Aeronautics and Astronautics

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A BiVO₄ photoanode was combined with bioinspired Mn₄O₄-cubane, which has a structure and composite similar to those of the oxygen-evolving complex (Mn₄CaO₅) in photosystem II. The hybrid photoanode exhibited a lower onset potential and higher photocurrent than the pristine photoanode because of the faster kinetics of the reaction and reduced rate of recombination of the carriers.

Original language	English
Pages (from-to)	4244-4247
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	30
DOIs	https://doi.org/10.1039/d0cc00955e
State	Published - 18 Apr 2020
Externally published	Yes

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title = "Promoting hole transfer for photoelectrochemical water oxidation through a manganese cluster catalyst bioinspired by natural photosystem II",

abstract = "A BiVO4 photoanode was combined with bioinspired Mn4O4-cubane, which has a structure and composite similar to those of the oxygen-evolving complex (Mn4CaO5) in photosystem II. The hybrid photoanode exhibited a lower onset potential and higher photocurrent than the pristine photoanode because of the faster kinetics of the reaction and reduced rate of recombination of the carriers.",

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AU - Gao, Bin

AU - Wang, Tao

AU - Li, Yang

AU - Fan, Xiaoli

AU - Gong, Hao

AU - Jiang, Cheng

AU - Li, Peng

AU - Huang, Xianli

AU - He, Jianping

PY - 2020/4/18

Y1 - 2020/4/18

N2 - A BiVO4 photoanode was combined with bioinspired Mn4O4-cubane, which has a structure and composite similar to those of the oxygen-evolving complex (Mn4CaO5) in photosystem II. The hybrid photoanode exhibited a lower onset potential and higher photocurrent than the pristine photoanode because of the faster kinetics of the reaction and reduced rate of recombination of the carriers.

AB - A BiVO4 photoanode was combined with bioinspired Mn4O4-cubane, which has a structure and composite similar to those of the oxygen-evolving complex (Mn4CaO5) in photosystem II. The hybrid photoanode exhibited a lower onset potential and higher photocurrent than the pristine photoanode because of the faster kinetics of the reaction and reduced rate of recombination of the carriers.

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U2 - 10.1039/d0cc00955e

DO - 10.1039/d0cc00955e

M3 - 文章

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AN - SCOPUS:85083373713

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JF - Chemical Communications

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ER -

Promoting hole transfer for photoelectrochemical water oxidation through a manganese cluster catalyst bioinspired by natural photosystem II

Abstract

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