Abstract
1,3-dipolar cycloaddition resulted from alkynyl and azido is cream of the crop in click chemistry. This reaction is high-efficiency and its reaction condition is moderate. It offers a new way to prepare block copolymer with various well-defined structures by combining 1,3-dipolar cycloaddition with controlled radical polymerization. The prepared block copolymer is with high purity and narrow molecular weight distribution. In this paper, the facile combination of 1,3-dipolar cycloaddition with three kinds of controlled radical polymerization on preparing linear and nonlinear block copolymer was reviewed. Moreover, the further development direction was prospected.
| Original language | English |
|---|---|
| Pages (from-to) | 607-611 |
| Number of pages | 5 |
| Journal | Chemistry Bulletin / Huaxue Tongbao |
| Volume | 74 |
| Issue number | 7 |
| State | Published - 18 Jul 2011 |
Keywords
- 1,3-Dipolar Cycloaddition
- Block copolymer
- Click chemistry
- Controlled radical polymerization